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Detection of the Fe-O-O-Fe intermediate in the oxidation reaction of ferrous porphyrins by resonance Raman spectroscopy
Actinide bis(porphyrinate) .pi.-radical cations and dications, including the x-ray crystal structure of [(TPP)2Th][SbCl6]
Synthesis and polymerization of .gamma.-trichloroethyl-L-glutamate N-carboxyanhydride: a polypeptide that can be functionalized with a nucleophilic agent
Asymmetric nitrogen. 67. Geminal systems. 41. Chiroptical properties of N-chloro and N-bromo derivatives of three-membered nitrogen heterocycles: aziridines and diaziridines
Intramolecular photochemical electron transfer. 4. Singlet and triplet mechanisms of electron transfer in a covalently linked porphyrin-amide-quinone molecule
Regarding the inherent dependence of resonance effects of strongly conjugated substituents on electron demand
A LAXS (large angle x-ray scattering) and EXAFS (extended x-ray absorption fine structure) investigation of conductive amorphous nickel tetrathiolato polymers
Chemically mediated fluorescence yield switching in nitroxide-fluorophore adducts: optical sensors of radical/redox reactions
Intrinsic fluorescence and HPLC measurement of the surface dynamics of lysozyme adsorbed on hydrophobic silica
Molecular recognition in aqueous media: donor-acceptor and ion-dipole interactions produce tight binding for highly soluble guests
Generation of simple enols by photooxidation. Keto-enol equilibrium constants of some aliphatic systems in aqueous solution
Equilibration of diastereomeric two-chain surfactants. Hydrophobic control of organic stereochemistry
Structure, resolution, and racemization of decakis(dichloromethyl)biphenyl
Negative hyperconjugation. The rotation-inversion barrier in .alpha.-fluoramines
Evidence for a cytochrome P-450-catalyzed allylic rearrangement with double-bond topomerization
Correction. Isotopically Sensitive Branching and Its Effect on the Observed Intramolecular Isotope Effects in Cytochrome P-450 Catalyzed Reactions: A New Method for the Estimation of Intrinsic Isotope Effects
Orbital-overlap factor in electron transfer: sensitivity of homogeneous self-exchange kinetics for some metallocenes to electronic structure
Formation, reactivity, and proposed structures of gas-phase triosmium cluster ions: H2Os3(CO)10+ and its dimers, trimers, and fragments
Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): structures, antiferromagnetic coupling, and properties in solution
Analysis of NMR and absorption spectroscopic data in bacteriorhodopsin: models for protein-chromophore interactions
Model reactions related to cytochrome P-450. Effects of alkene structure on the rates of epoxide formation
Asymmetric dihydroxylation via ligand-accelerated catalysis
Antineoplastic agents. 147. Isolation and structure of the powerful cell growth inhibitor cephalostatin 1
Electrochemistry at the water/air interface. Lateral electron transport in Langmuir monolayers
The OPLS[optimized potentials for liquid simulations] potential functionsfor proteins, energy minimizations for crystals of cyclic peptidesand crambin
Molecular and macromolecular nonlinear optical materials. Probing architecture/electronic structure/frequency doubling relationships via an SCF-LCAO MECI .pi. electron formalism
Structure and chemistry of chemisorbed phosphorus trifluoride, phosphorus difluoride and phosphorus monofluoride on nickel(111): electron stimulated desorption ion angular distribution study
Stereoselective total synthesis of (.+-.)-atisine via intramolecular double Michael reaction
Probing ergot alkaloid biosynthesis: identification of advanced intermediates along the biosynthetic pathway
Characterization of a crystalline synthetic analog of copper(II)-bleomycin
Laser induced triplet excitons in the columnar phases of an octasubstituted metal free phthalocyanine
Theory of vibrational circular dichroism: trans-2,3-dideuteriooxirane
Enzymic synthesis of macrocyclic lactones
Gas-phase chemistry of the silaacetylide anion, HCSi-
A single transition state in the reaction of aryl diphenylphosphinate esters with phenolate ions in aqueous solution
Radical cation cyclization of 1,5-hexadiene to cyclohexene via the cyclohexane-2,5-diyl radical cation intermediate
The acidity of benzyl ketones in aqueous solution. Evaluation of the intrinsic acidifying effect of a phenyl group
Heterobimetallic complexes with (.mu.-phenoxo)bis(.mu.-carboxylato) cores
Theoretical investigation of the thermal ring opening of bicyclobutane to butadiene. Evidence for a nonsynchronous process
A novel optically active host: design, computer graphics, synthesis, and diastereomeric complex formation in aqueous solution
Methyl radical formation over lithium-doped magnesium oxide. Molecular orbital theory
Intrazeolite chemistry of nickel(0) complexes and Ni(0,II) clusters studied by EXAFS, solid-state NMR and FT-IR spectroscopy
Convenient preparation and structures of selenometalates MoSe42-, WSe42- and MoSe92- from polyselenide anions and metal carbonyls
Metazidohemerythrin models featuring a bis-benzimidazole tripod ligand. Structure and spectroscopy of .mu.-oxobis(.mu.-benzoato)bis(bis(2-benzimidazolylmethyl)amine)diiron(III)
Effect of molecular dimension on the rate of return electron transfer within photoproduced geminate radical ion pairs
Carboxylic acid complexation by a synthetic analog of the "carboxylate-binding pocket" of vancomycin
Synthesis and structure of the polymetallic yttrium alkoxide complex Y3(.mu.-OCMe3)(.mu.3-Cl)(.mu.-OCMe3)3(OCMe3)4(THF)2 and related complexes: Ln3(.mu.3-OR)(.mu.3-X)(.mu.-OR)3 building blocks in yttrium and lanthanide alkoxide chemistry
High-pressure study on intramolecular excimer formation of 1,3-di-1-pyrenylpropane in various solvents
Iron-57 hyperfine coupling tensors of the FeMo cluster in Azotobacter vinelandii MoFe protein: determination by polycrystalline ENDOR spectroscopy
The acidity of 2-indanone. The effect of a conjugated phenyl group on enolate stability
Transition-metal-mediated photochemical disproportionation of carbon dioxide
Fingerprints of the carbon-nitrogen bond formation between ethylenediamine and an aldose on cobalt(III) complexes. Isotopic multiplets in the carbon-13 NMR spectra of cobalt(III) complexes with partially deuteriated coordinated amino groups
Molecular and electronic structure of the low-lying electronic states of cycloalkenylidenes: cyclopropenylidene
Theoretical elucidation of the origin of the anomalously high acidity of Meldrum's acid
Masthead
Reaction of diphenylmethyl cations in a strong acid. Participation of carbodications with positive charge substantially delocalized over the aromatic rings
Acidity of (Z)- and (E)-methyl acetates: relationship to Meldrum's acid
Cyclic cystine peptides. Antiparallel .beta.-sheet conformation for the 20-membered ring in Boc-Cys-Val-Aib-Ala-Leu-Cys-NHMe
Direct conversion of aldehydes to seleno- and thioaldehydes
Total synthesis of glycinoeclepin A
Interrelationship between carboxyvinylketenes, methyleneketenes, vinylketenes, and hydroxyacetylenes
Conformational stability of dimethyl phosphate anion in water: liquid-state free energy simulations
Rapid protein sequencing by the enzyme-thermospray liquid chromatographic/mass spectrometric method
Matrix photochemistry of (.eta.5-cyclopentadienyl)bis(ethene)rhodium and (.eta.5-cyclopentadienyl)(ethene)carbonylrhodium: a test-bed for intermediates in C-H activation
Cobalt and manganese complexes of a Schiff base biquinone radical ligand
Bacterial organomercurial lyase: novel enzymic protonolysis of organostannanes
Degradation of DNA-RNA hybrids by bleomycin: evidence for DNA strand specificity and for possible structural modulation of chemical mechanism
Structures and transformations of the bacteriochlorophylls e and their bacteriopheophorbides
Upper electronic excited states of quadruply bonded M2X4(PMe3)4 complexes
Low-symmetry, mixed-valent, .mu.-oxo technetium complexes with pyridine and halide ligands
A convenient method for the generation of o-quinodimethanes by proton induced 1,4-elimination of o-(1-hydroxyalkyl)benzyltributylstannanes
Excited-state behavior of tryptamine and related indoles. Remarkably efficient intramolecular proton-induced quenching
Biosynthesis of triterpenes, ursolic acid and oleanolic acid in tissue cultures of Rabdosia japonica Hara fed [5-13C2H2]mevalonolactone and [2-13C2H3]acetate
Infrared vibrational circular dichroism in the amide III spectral region of peptides
Intramolecular exchange effects in multiple quantum spectroscopy
Corrections. Micellar Control of Organic Reactions: Propellane Substrates as Stereochemical Probes for Micellar Binding
Corrections. The Separation of the Intramolecular Isotope Effect for the Cytochrome P-450 Catalyzed Hydroxylation of N-Octane int Its Primary and Secondary Components
A general approach to the stereoselective synthesis of spiroketals. A total synthesis of the pheromones of the olive fruit fly and related compounds
Fluorescence-quenching mechanism of tryptophan. Remarkably efficient internal proton-induced quenching and charge-transfer quenching
Evidence for a common batho intermediate of rhodopsin and isorhodopsin
Reactivities of acrylic and methacrylic acids in a nucleophilic addition model of their biological activity
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. A theoretical and experimental investigation of the electronic structure of Ru2(CO)4(R-DAB)(.mu.-CO) and Ru2(CO)4(R-DAB)(.mu.-HC.tplbond.CH)
Thermochemistry of the orthogonal butadienes (Z,Z)-3,4-dimethylhexa-2,4-diene and 2,3-di-tert-butylbuta-1,3-diene
Benzyne, cyclohexyne, and 3-azacyclohexyne and the problem of cycloalkyne versus cycloalkylideneketene genesis
Photoaddition and photoreduction of chloranil with arenes via singlet and triplet excited complexes. Effects of irradiation wavelength and radical-ion pair spin multiplicity
Unprecedented rearrangement of a diphosphene .eta.1.eta.2-bonded to iron. Synthesis and x-ray structure of Fe4 complexes containing either a .mu.4 spiro phosphorus atom or a 1, 1, 2 trimetalla diphosphorus ligand .scharw.P:P-
Book Reviews
Odd-electron .sigma. bonds
Electronic structure of tetrakis(isopropylthio)thieno[3,4-c]thiophene studied by photoelectron and electronic absorption spectroscopies combined with MO calculations
Reactions of MCl5 (M = niobium or tantalum) with excess phenyllithium: structural characterization of bisbenzyne/polyphenyl derivatives of niobium and tantalum
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