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EPR-ENDOR of the electronic structure from two nitrogenously ligated bis(.mu.-oxo)-manganese(III)-manganese(IV) model complexes spectroscopically relevant to the multi-manganese center of photosystem II
Vanadate interactions with bovine copper,zinc-superoxide dismutase as probed by vanadium-51 NMR spectroscopy
Reactions of anionic nucleophiles with .alpha.-D-glucopyranosyl fluoride in aqueous solution through a concerted, ANDN (SN2) mechanism
Investigations on 1,2-, 1,3-, and 1,4-asymmetric induction in intramolecular Reformatskii reactions promoted by samarium(II) iodide
Pendant-capped porphyrins. 1. The synthesis of a biphenyl pendant-capped iron(III) porphyrin model of catalase
Cationic ring expansion of an ozonide to a 1,2,4-trioxane
Crystal structure of lithium diisopropylamide (LDA): an infinite helical arrangement composed of near-linear nitrogen-lithium-nitrogen units with four units per turn of helix
Computer Software Reviews
Carbohydrates as chiral auxiliaries: asymmetric cyclopropanation reaction of acyclic olefins
Relationship of STM and AFM images to the local density of states in the valence and conduction bands of rhenium selenide (ReSe2)
A computer-assisted method for estimation of the partition coefficient. Monte Carlo simulations of the chloroform/water log P for methylamine, methanol, and acetonitrile
Different reversibility of bromonium vs .beta.-bromocarbonium ions formed during the electrophilic bromination of substituted stilbenes. Evidence for rate determination during the product-forming step
Synthesis and reactions of rhenium complex Cp*(CO)2Re:Re(CO)2Cp*
Solution structure elucidation of early transition metal polyoxoalkoxides using oxygen-17 NMR spectroscopy
Proton NMR hyperfine shift pattern as a probe for ligation state in high-spin ferric hemoproteins: water binding in metmyoglobin mutants
From 1-D to 3-D ferrimagnets in the EDTA family: magnetic characterization of the tetrahydrate series MtM(M'EDTA)2.cntdot.4H2O [Mt, M, M' = cobalt(II), nickel(II), zinc(II)]
New mode of porphyrin complexation with nucleobase
Rearrangement and dissociative reactions of the methanol radical cation (CH3OH.bul.+): a comparison of theory and experiment
1,2-Bridged cyclopropenes
"Kinetic" higher order cyanocuprates: applications to biaryl synthesis
Rotational spectra of biomolecules: histamine
Secondary hydrogen/deuterium isotope effects in methyl-transfer reactions decrease with increasing looseness of the transition structure
Periodic-chaotic sequences in a detailed mechanism of the peroxidase-oxidase reaction
Structures and bonding of Group IVA sulfur and oxygen propellane derivatives
Organic photochemistry. 93. Photochemical and photophysical studies of tetracycline
Probing the acceptor specificity of .beta.-1,4-galactosyltransferase for the development of enzymatic synthesis of novel oligosaccharides
A photochemical [4+4] method for the construction of annulated eight-membered rings
The chemical consequences of conformational polymorphism: the phase-transition-dependent photochemistry of crystalline 1,14-cyclohexacosanedione
Masthead
Laser manipulation and ablation of a single microcapsule in water
Theoretical investigation of the proton-induced decomposition of 4,5-dihydro-1,2,3-triazole to form the aziridinium ion: instability of the (2-aminoethyl)diazonium ion
Ligand field strengths and oxidation states from manganese L-edge spectroscopy
Synthesis and analysis of 506BD, a high-affinity ligand for the immunophilin FKBP
Isomerism in the Mo2(.mu.-O2CCF3)4/bpy reaction system: thermal and photochemical conversion of the ion-pair complex [Mo2(.mu.-O2CCF3)2(bpy)2](O2CCF3)2 to the unbridged neutral isomer Mo2(.eta.1-O2CCF3)4(bpy)2
Tertiary amine stabilized dialane
Crystal structure of an .eta.2-acetonitrile complex of tungsten(II): acetonitrile as a four-electron donor
Torsional effects on the conformations of two diastereomeric tetracyclic bis(hydrazines)
1,3-Bridged cyclopropenes
Acylation of alkenes generated in situ by hydride transfer from isoalkanes. Synthesis of pentalenones, hydrindenones, and cyclopentenones
Conformational potential energy surface of glycine: a theoretical study
Rotational energy surfaces of aza- and phospha-1,3-butadienes. A theoretical study
Is halogen-lithium exchange intramolecularly competitive with removal of an acidic hydrogen? Reinvestigation of a recent claim
A mechanism for the ferromagnetic coupling in decamethylferrocenium tetracyanoethenide
A carbene to biradical rearrangement: reaction paths from (8-methyl-1-naphthyl)carbene to acenaphthene
Structure and absolute stereochemistry of the four N-phenylprotoporphyrin IX regioisomers isolated from phenylhydrazine-treated myoglobin
New mechanistic and stereochemical insights on the biosynthesis of sterols from 2,3-oxidosqualene
A novel photochemical route to the mitomycin and FR-900482 series
Electron paramagnetic resonance study of the reaction of silver atoms with C60 in cyclohexane on a rotating cryostat
Photochemistry of intercalated quaternary diazaaromatic salts
Mechanistic studies on a placental aromatase model reaction
Nearest-neighbor recognition in phospholipid bilayers. Probing lateral organization at the molecular level
Topography of cyclodextrin inclusion complexes. 28. Neutron diffraction study of the hydrogen bonding in partially deuterated .gamma.-cyclodextrin.cntdot.15.cntdot.7D2O at T = 110 K
General-acid and general-base catalysis of the cleavage of .alpha.-D-glucopyranosyl fluoride
The total synthesis of cystodytins
Synthesis of bis(buckminsterfullerene)nickel cation, Ni(C60)2+, in the gas phase
Chemical model studies on the mutagenesis of benzofuran dioxetanes in the Ames test: evidence for the benzofuran epoxide as ultimate mutagen
Liposome-mediated enzymatic synthesis of phosphatidylcholine as an approach to self-replicating liposomes
Novel class of asymmetric zwitterionic rotaxanes based on .alpha.-cyclodextrin
Book Reviews
Gas-phase structure and conformations of malonyl difluoride (COF-CH2-COF) and difluoromalonyl difluoride (COF-CF2-COF). An electron diffraction and ab initio study
Synthesis and x-ray crystal structure of the first diphosphirenium salt
Mirror-image DNA
An experimentally based family of potential energy surfaces for hydride transfer between NAD+ analogs
Mechanistic and synthetic aspects of intramolecular base-catalyzed migration of the thiophosphoryl group from sulfur to oxygen in sugar .beta.-hydroxyphosphorodithioate systems
Is the McConnell mechanism a suitable strategy for the design of molecular ferromagnets?
Fragmentation of substituted acetophenones and halobenzophenone ketyls. Calibration of a mechanistic probe
Studies on the mechanism and origin of stereoselective opening of chiral dioxane acetals
Purification of the 2,3-oxidosqualene-lanosterol cyclase from Saccharomyces cerevisiae
Calixcrowns as selective potassium cation carriers in supported liquid membranes
Diastereoselective synthesis of phycocyanobilin-cysteine adducts
Tetraphenyl distibine: a most useful reagent for discriminating radical reactions
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