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Insertion of transition metals into the phosphorus-phosphorus bond of 1,2-dihydro-1,2-diphosphetes: toward the phosphorus analogs of metal dithiolene complexes
Interpretation of spectroscopic changes upon adduct formation and their use to determine electrostatic and covalent (E and C) parameters
Electron spin-echo envelope modulation spectroscopy of Mn2+.cntdot.GDP complexes of N-ras p21 with selective nitrogen-15 labeling
Ring-opening metathesis polymerization of substituted bicyclo[2.2.2]octadienes: a new precursor route to poly(1,4-phenylenevinylene)
Syntheses of racemic and both chiral forms of cyclopropane-1,2-d2 and cyclopropane-1-13C-1,2,3-d3
Reactivity of tunichromes: reduction of vanadium(V) and vanadium(IV) to vanadium(III) at neutral pH
Jahn-Teller distortion predicted for metallocarbohedrenes: an ab initio SCF geometry optimization of the lowest singlet and triplet states of titanium carbide (Ti8C12) in the Th and D2h point groups
Energy dependence and dynamics of gas-phase ion-molecule reactions
NMR spectroscopic and computational characterization of 1-(p-anisyl)vinyl cations. Methoxy group rotation as a probe of .beta.-carbon-silicon, .beta.-carbon-carbon and .beta.-carbon-hydrogen hyperconjugation
Charge separation in donor-chromophore-acceptor complexes: inverted region behavior in reverse electron transfer reactions
Analogies between the concepts of molecular chemistry and solid-state physics concerning structural instabilities. Electronic origin of the structural modulations in layered transition metal dichalcogenides
Synthesis and characterization of an aluminosilsesquioxane framework that violates Loewenstein's rule
Nucleotide and deduced amino acid sequences of the oxidosqualene cyclase from Candida albicans
Magnesium porphyrin radical cations: a theoretical study of substituent effects on the ground state
Conformations of Arg-Gly-Asp containing heterodetic cyclic peptides: solution and crystal studies
Synthesis of a DNA knot containing both positive and negative nodes
Observation of a series of degenerate cyclic double, triple, and quadruple proton transfers in solid pyrazoles
Mononuclear nickel(II) complex with [NiN3S2] chromophore that readily affords the nickel(I) and nickel(III) analogs: probe into the redox behavior of the nickel site in [iron-nickel] hydrogenases
Synthesis, chemistry, and properties of a monoalkylated buckminsterfullerene derivative, tert-BuC60 anion
Rigid-rod molecules: carborods. Synthesis of tetrameric p-carboranes and the crystal structure of bis(tri-n-butylsilyl)tetra-p-carborane
Trimesoyltris(3,5-dibromosalicylate): specificity of reactions of a trifunctional acylating agent with hemoglobin
Chemical-enzymic synthesis and conformational analysis of sialyl Lewis X and derivatives
Photochemistry in biological matrices: activation of racemic mixtures and interconversion of enantiomers
Total synthesis of (+)-calyculin A
Facile .alpha./.beta. diastereomerism in organocobalt corrinoids: synthesis, characterization, and complete proton and carbon-13 NMR assignments of .alpha.-5'-deoxyadenosylcobinamide and .alpha.-5'-deoxyadenosylcobalamin
Total synthesis of (.+-.)-byssochlamic acid
Book Reviews
Photochemically and photoenzymatically cleavable DNA
Electrochemical synthesis of ceramic materials. 2. Synthesis of aluminum nitride (AlN) and an AlN polymer precursor: chemistry and materials characterization
Structure and stability of complexes of glycine and glycine methyl analogs with H+, Li+, and Na+
Bond alternation in triannelated benzenes: dissection of cyclic .pi. from Mills-Nixon effects
Fullerene dications as initiators of polymerization with 1,3-butadiene in the gas phase: chemistry directed by electrostatics?
Neighboring group activation of acetal cleavage: a novel nonacidic strategy for the tandem formation of cyclic ethers.
A modular approach for ligand design for asymmetric allylic alkylations via enantioselective palladium-catalyzed ionizations
Kinetics of thermal geometric isomerizations of three sets of isotopically labeled cyclopropanes followed by tunable diode laser spectroscopy
Tetraphilin: a four-helix proton channel built on a tetraphenylporphyrin framework
Recognition of guanine and adenine in DNA by cytosine and thymine containing peptide nucleic acids (PNA)
Photosensitized formation of 7,8-dihydro-8-oxo-2'-deoxyguanosine (8-hydroxy-2'-deoxyguanosine) in DNA by riboflavin: a nonsinglet oxygen-mediated reaction
Conversion of alkenes to enol silyl ethers of acylsilanes by iridium-catalyzed reaction with a hydrosilane and carbon monoxide
Development of photo cis-platinum reagents. Reaction of cis-dichlorobis(1,10-phenanthroline)rhodium(III) with calf thymus DNA, nucleotides and nucleosides
Enantioselective catalysis of the triplex Diels-Alder reaction: a study of scope and mechanism
Mechanisms of viologen-mediated charge separation across bilayer membranes deduced from mediator permeabilities
EXAFS evidence for a "cysteine switch" in the activation of prostromelysin
A phosphorus-31 NMR stereochemical and kinetic study of the alkaline hydrolysis of cis-nucleoside 3',5'-cyclic aryl [18O]monophosphates and unlabeled analogs
The first design and synthesis of a steroidal peptidomimetic. The potential value of peptidomimetics in elucidating the bioactive conformation of peptide ligands
1,2-Asymmetric induction in the tin-hydrogen bond insertion reaction of aliphatic Fischer carbene complexes
Discovery of a labile nickel ion required for CO/acetyl-CoA exchange activity in the NiFe complex of carbon monoxide dehydrogenase from Clostridium thermoaceticum
Biocatalysis and nineteenth century organic chemistry: conversion of D-glucose into quinoid organics
Design and evaluation of a tightly binding fluorescent ligand for influenza A hemagglutinin
NMR chemical shifts: a tool to characterize distortions of peptide and protein helices
Nanoarchitectures. 3. Aggregation of hexa(phenylacetylene) macrocycles in solution: a model system for studying .pi.-.pi. interactions
Cannizzaro-based molecular oxygen-dependent cleavage of DNA by quinocarcin. [Erratum to document cited in CA116(5):34018r]
Masthead
Solvent structure around cations determined by proton ENDOR spectroscopy and molecular dynamics simulation
Control of dispersity in stereoselective telomerizations: the addition/cyclization/transfer strategy
Direct electron transfer involving free-solute ferrocene in fluid electrolyte on an oxocuprate (Bi(Pb) 2223) electrode in the superconducting state
The "CUPID" method for calculating the continuous probability distribution of rotamers from NMR data. [Erratum to document cited in CA117(4):34037s]
Probing the exchange interaction through micelle size. 1. Probability of recombination of triplet geminate radical pairs
Kinetic EPR studies of the decay of tert-butyl alkoxy, silyloxy, germyloxy, and stannyloxy nitroxides
An allyl radical-dioxygen caged pair mechanism for cis-allylperoxyl rearrangements
Fluorometric chemodosimetry. Mercury(II) and silver(I) indication in water via enhanced fluorescence signaling
Structural studies of potent constrained RGD peptides
Stereochemical dissection of a carbene fragmentation reaction
Zirconium and hafnium polyhydrides. 2. Preparation and characterization of M3H6(BH4)6(PMe3)4 and M2H4(BH4)4(dmpe)2
Homogeneous Ziegler-Natta polymerization of functionalized monomers catalyzed by cationic Group IV metallocenes
Equilibration between the fluorescent and zwitterionic phantom states in alkyl-substituted tetraphenylethylenes
Total synthesis of (.+-.)-breynolide, an aglycon derivative of the orally active hypocholesterolemic agent breynin A
Magnetic resonance studies of polypeptides adsorbed on silica and hydroxyapatite surfaces
Computer Software Reviews
Redox-controlled Bergman cycloaromatizations. Designed enediynes with DNA-cleaving properties and antitumor activity
Efficient transfer-dehydrogenation of alkanes catalyzed by rhodium trimethylphosphine complexes under dihydrogen atmosphere
Reactions of thiyl radicals with transition-metal complexes
.pi.-Bond strengths of H2X:YH2: X = Ge, Sn; Y = C, Si, Ge, Sn
Intrinsic competition between elimination and substitution mechanisms controlled by nucleophile structure
Uranyl UO2-salenes: neutral receptors for anions with a high selectivity for dihydrogen phosphate
A short synthesis of (+)-lycoricidine
Functional analogs of CC-1065 and the duocarmycins incorporating the 9a-(chloromethyl)-1,2,9,9a-tetrahydrocyclopropa[c]benz[e]indol-4-one (C2BI) alkylation subunit: synthesis and preliminary DNA alkylation studies
Contribution to the development of new substitution patterns of optically active .beta.-lactams: synthesis of homochiral 4-(1-aminoalkyl)azetidin-2-ones from N-(tert-butyloxycarbonyl) .alpha.-amino aldehyde-derived imines via asymmetric Staudinger reaction
Enzymic asymmetrization in organic media: synthesis of unnatural glucose from cycloheptatriene.
Clusters of phosphorus: a theoretical investigation
Dissociative electron transfer. Ab initio study of the carbon-halogen bond reductive cleavage in methyl and perfluoromethyl halides. Role of the solvent
Inhibition of intramolecular electron transfer in sulfite oxidase by anion binding
Tuning the stereochemistry of pentacoordinate cobalt(III) halide complexes: a rare case of trigonal bipyramidal stereochemistry for cobalt(III)
The diosmium tetrahydroxydisiloxane, [OsCl(CO)(PPh3)2Si(OH)2]2O, from the coordinatively unsaturated trihydroxysilyl complex, Os(Si[OH]3)Cl(CO)(PPh3)2
Synthesis and characterization of .mu.2-.eta.2- and .mu.2-.eta.3-CO2 complexes of iron and rhenium
Photoinduced electron transfer reactions: nitrogen-oxygen bond cleavage in reduced N-(aryloxy)pyridinium and N,N'-dialkoxy-4,4'-bipyridinium salts
Main chain and side chain chiral methylated somatostatin analogs: syntheses and conformational analyses
(Trifluoroethylidyne)sulfur trifluoride, F3CC.tplbond.SF3: two solid-state structures and reactivity as a carbene
Protein electrochemistry at high pressure
Mechanism of peptide release from major histocompatibility complex class II molecules
Formation of a novel [cyclic] P-B-N-C ring via an intramolecular carbon-hydrogen activation process
The total synthesis of angular [4]- and [5]phenylene
A stable carbene-alane adduct
Studies on the thermal generation and reactivity of a class of (.sigma.,.pi.)-1,4-biradicals
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