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Antiparallel side-by-side heterodimer for sequence-specific recognition in the minor groove of DNA by a distamycin/1-methylimidazole-2-carboxamide-netropsin pair
CH-.pi. interaction as an important driving force of host-guest complexation in apolar organic media. Binding of monools and acetylated compounds to resorcinol cyclic tetramer as studied by proton NMR and circular dichroism spectroscopy
Metal ion-induced self-assembly of functionalized 2,6-oligopyridines. 1. Ligand design, synthesis, and characterization
Formation of methyl radicals during the oxidative addition of iodomethane to a single-crystal copper surface
Evidence of calcium(2+)-dependent carbohydrate association through ion spray mass spectrometry
Mechanism-based enzyme inactivation via a diactivated cyclopropane intermediate
Organic cation salts of the tetrafluoroaluminate anion. Yes, it does exist, and yes, it is tetrahedral
Structural and thermodynamic studies of d(C3T4C3) in acid solution: evidence for formation of the hemiprotonated CH+.cntdot.C base pair
Ab initio calculations of ten carbon/nitrogen cubanoids
Two-step sequential light-induced electron transfer in a simple trichromophoric donor-donor-acceptor system
Active-site electronic structure contributions to electron-transfer pathways in rubredoxin and plastocyanin: direct versus superexchange
Reversible reaction of dioxygen (and carbon monoxide) with a copper(I) complex. X-ray structures of relevant mononuclear Cu(I) precursor adducts and the trans-(.mu.-1,2-peroxo)dicopper(II) product
Evidence for a planar cyclically conjugated 8.pi. system in the excited state: large Stokes shift observed for dibenz[b,f]oxepin fluorescence
Masthead
Asymmetric aldol reactions: a novel model for switching between chelation- and non-chelation-controlled aldol reactions
Solid-state nitrogen-15 NMR studies of the nitroso group in the nitrosobenzene dimer and p-nitroso-N,N-dimethylaniline
Reversible 3 + 2 cycloaddition of ethylene to the C:Re.tplbond.C unit in rhenium complexes of the type Re(.tplbond.CCMe3)(:CHR')(OR)2
.eta.3-Bonding of phenylallenyl in a zirconocene complex
Book Reviews
Rearrangement of alkynyl and vinyl carbenoids via the rhodium(II)-catalyzed cyclization reaction of .alpha.-diazo ketones
Molecular weight of C60 in solution by vapor pressure osmometry
Covalent structure of a nitrogen mustard-induced DNA interstrand cross-link: an N7-to-N7 linkage of deoxyguanosine residues at the duplex sequence 5'-d(GNC)
Hydride affinities of carbenium ions in acetonitrile and dimethyl sulfoxide solution
Pentacoordinated molecules. 95. Influence of phosphorus-sulfur bonding in the formation of octahedrally coordinated cyclic pentaoxyphosphoranes
Synthesis and characterization of lithium, sodium, and potassium porphyrin complexes. X-ray crystal structures of Li2(C6H12O2)2TMPP, Na2(THF)4OEP, and K2(pyridine)4OEP
Cavity-size-dependent dissociation of crown ether/ammonium ion complexes in the gas phase
Hydrogenation of adsorbed ethylene on zinc oxide (ZnO(0001)) surface: probed by coherent anti-Stokes Raman scattering spectroscopy using guided waves
Ribonucleoside membrane transport by a new class of synthetic carrier
(E)-2-Butanediazoic acid decomposes via a diazonium ion intermediate
Configurational stability of chiral, nonconjugated nitrogen-substituted organolithium compounds generated by tin-lithium exchange of N-[(1-tri-n-butylstannyl)alkyl]imidazolidin-2-ones and -oxazolidin-2-ones
Aqueous solubilization of a synthetic charge-transfer receptor via cycloamylose inclusion
End-on versus side-on bonding of dinitrogen to dinuclear early transition-metal complexes
Synthesis of cyclic bifunctional organomagnesium compounds. X-ray crystal structures of tetrameric organomagnesium clusters
Helium iodide photoelectron, mid-infrared, and ab initio studies of the unstable fluoroisocyanatoboranes F2BNCO and FB(NCO)2
Glycine conformational analysis
Ab initio study of Diels-Alder reactions of cyclopentadiene with ethylene, isoprene, cyclopentadiene, acrylonitrile, and methyl vinyl ketone
NMR evidence for specific intercalation of .DELTA.-rh(phen)2.phi.3+ in [d(GTCGAC)2]
Stronger acceptors can diminish nonlinear optical response in simple donor-acceptor polyenes
Interference between J-couplings and cross-relaxation in solution NMR spectroscopy: consequences for macromolecular structure determination
Computer Software Reviews
The IOF6- anion: the first example of a pentagonal bipyramidal AX5YZ species
Opening, desulfurization, and hydrogenation of thiophene at iridium. An experimental study in a homogeneous phase
Simulation of conformational dynamics with the MM3 force field: the pseudorotation of cyclopentane
Reversible oxidation of a strained alkene by Cp*ReO3
Variable regiochemistry in the stoichiometric and catalytic hydroamination of alkynes by imidozirconium complexes caused by an unusual dependence of the rate law on alkyne structure and temperature
Analysis of the distance dependence and magnitude of the .pi.+,.pi.- and .pi.+*,.pi.-* splittings in a series of diethynyl[n]staffanes: an ab initio molecular orbital study
"Locking" the bowl-shaped geometry of corannulene: cyclopentacorannulene
Proton gated emission from porous silicon
Novel synthesis of sulfonimidoyl halides and sulfonimidates from N-silylated sulfonamides and dihalophosphoranes
Thermochemistry of zirconium and niobium organometallic compounds
Microscopic medium effects on a chemical reaction. A theoretical study of decarboxylation catalyzed by cyclodextrins as an enzyme model
Ireland-Claisen rearrangements of enediyne lactones: tandem Claisen-Bergman strategy for stereocontrolled tetrahydronaphthalene synthesis
Vibrational structure in the photoelectron spectrum of cyclobutadiene as a probe of structure
Observation of a complex formed between RhH2 and methane molecules
NMR studies of a cobalt-substituted zinc finger peptide
A family of stable iron(I) .sigma.-alkynyl complexes. Synthesis, characterization, structure, and electron-transfer chemistry
Biomimetic synthesis of a cyclopropane containing eicosanoid from the coral Plexaura homomalla. Assignment of relative configuration
First total synthesis of Lycopodium alkaloids of the magellanane group. Enantioselective total syntheses of (-)-magellanine and (+)-magellaninone
Generation and characterization of isomeric iron-silylene and iron-silene cationic complexes in the gas phase. [Erratum to document cited in CA118(17):169276k]
Copper L-edge spectral studies: a direct experimental probe of the ground-state covalency in the blue copper site in plastocyanin
Selenonthiol esters: isolation and characterization
Diastereoselective and regioselective photooxygenation of a chiral allylic amine and its acyl derivatives: stereochemical evidence for a steering effect by the amino group in the ene reaction of singlet oxygen
Do pentacoordinate oxyphosphorane intermediates always exist?
Preparation, molecular structure, and Diels-Alder cycloaddition chemistry of .beta.-functionalized alkynyl(phenyl)iodonium salts
Poly(alkyl/aryloxothiazenes): inorganic polymers with a sulfur(VI)-nitrogen backbone. Synthesis, characterization, and theoretical calculations
Dilead structural units in lead halide and hydroxo/oxo molecules, clusters and extended structures found in molten salts, aqueous solutions, and the solid state
Computational study of ring- and metal-protonated ferrocene
The ab initio calculation of inner sphere reorganization energies of inorganic redox couples
Structure and total synthesis of sporol and neosporol
Synthesis of a novel hydrogel based on a coordinate covalent polymer network
Molybdenum-mediated oxygen-atom transfer: an improved analog reaction system of the molybdenum oxotransferases
Scope and mechanism of alkene hydrogenation/isomerization catalyzed by complexes of the type R2E(CH2)2M(CO)(L) (R = Cp, Me, Ph; E = phosphorus, tantalum; M = rhodium, iridium; L = CO, PPh3)
Reactions of atomic and diatomic iron with allene in solid argon
Theoretical determination of proton affinity differences in zeolites
Diethylaluminum chloride complexes of an N-acyloxazolidinone: NMR investigation
Reversible carbon-silicon bond cleavage in the methylene/silyl complex Cp*2Ru2(.mu.-CH2)(.mu.-Cl)(SiMe3)
Cross-reactions of various microbial, fungal, mold, and yeast polysaccharides in antipneumococcal and other antisera
High-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: heterolytic cleavage of hydroperoxides
Dynamics of cis/trans isomerization of the cysteine6-proline peptide bonds of oxytocin and arginine-vasopressin in aqueous and methanol solutions
Theoretical studies on hydration of pyrrole, imidazole, and protonated imidazole in the gas phase and aqueous solution
Potential of mean force for the isomerization of DMF in aqueous solution: a Monte Carlo QM/MM simulation study
A designed synthetic analog of cobalt(III)-bleomycin with enhanced DNA-binding and photocleaving activity
Mechanism and stereochemistry for nucleophilic attack at carbon of platinum(IV) alkyls: model reactions for hydrocarbon oxidation with aqueous platinum chlorides
Structure of a novel 60-membered macrolide, quinolidomicin A1
Gas-phase fragmentations of anionic complexes between peptides and alkaline earth metal ions: structure-specific side-chain interactions
Purple acid phosphatase: a diiron enzyme that catalyzes a direct phospho group transfer to water
Biosynthesis of lycopodine: incorporation of acetate via an intermediate with C2v symmetry
General strategy for the stereocontrolled synthesis of Strychnos alkaloids: a concise synthesis of (.+-.)-dehydrotubifoline
Structure of nickel dichloride
Self-organization of bilayer assemblies in a fluorocarbon medium
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