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Total Chemical Synthesis of a Folded .beta.-Sandwich Protein Domain: An Analog of the Tenth Fibronectin Type 3 Module
Reaction of a Stable Silylene with Covalent Azides: A New Synthesis for Silaimines
Aggregate Formation and Photoreactivity in Phospholipid Vesicles and Langmuir-Blodgett Multilayers: Topologically Controlled Photodimerization of Amphiphilic Styrenes
An ab initio molecular orbital study of the mechanism of the rhodium(I)-catalyzed olefin hydroboration reaction
Electronic Structures and Gas-Phase Reactivities of Cationic Late-Transition-Metal Oxides
Synthesis and 3He NMR Studies of C60 and C70 Epoxide, Cyclopropane, and Annulene Derivatives Containing Endohedral Helium
Demonstration of the Chemical Competence of an Iminodiazonium Ion to Serve as the Reactive Intermediate of a Schmidt Reaction
Correction. Isomerization of (π-Allyl)Palladium Complexes via Nucleophilic Displacement by Palladium(0). A Common Mechanism in Palladium(0)-Catalyzed Allylic Substitution
The Catalytic Cyclooligomerization of Thietane by Trirhenium Cluster Complexes. A New Route to Polythiaether Macrocycles
Preparation and Conformation of Hexaarmed Star Poly(.beta.-benzyl-L-aspartates) Synthesized Utilizing Hexakis(4-aminophenoxy)cyclotriphosphazene
Aryldisilane photochemistry. A kinetic and product study of the mechanism of alcohol additions to transient silenes
"Freezing-in" of Carbonylhemoglobin's CO Conformer Population by Hyperquenching of Its Aqueous Solution into the Glassy State: An FTIR Spectroscopic Study of the Limits of Cryofixation
Photoexcited Proton Transfer from Enhanced Photoacids
Guided Ion Beam Studies of the Reactions of Ti+, V+, and Cr+ with Silane. Electronic State Effects, Comparison to Reactions with Methane, and M+-SiHx (x = 0-3) Bond Energies
Peptide Models of a Hydrophobic Cluster at the C-Terminus of the .beta.-Amyloid Protein
Low-Energy Electronic Absorptions in 17-Electron Organometallic Piano Stool Radicals
Book Reviews
Observation of New Intermediates in Hydrogenation Catalyzed by Wilkinson's Catalyst, RhCl(PPh3)3, Using Parahydrogen-Induced Polarization
Scanning Tunneling Microscopic Study with Atomic Resolution of the Dissolution of Cu(111) in Aqueous Chloride Solutions
Direct Asymmetric .alpha.-Alkylation of Phenylalanine Derivatives Using No External Chiral Sources
Electrochemical Polymerization of Pyrrole-Containing Self-Assembled Alkanethiol Monolayers on Au
Total Synthesis of 8-epi-PGF2.alpha.. A Novel Strategy for the Synthesis of Isoprostanes
Hammett Reaction Constant for a Terminal Methoxyphosphinidene Complex. Absence of Ambiphilicity
Probing the Molecular Primary and Secondary Structures of Saturated Hydrocarbons by X-ray Photoionization Spectroscopy
NMR and X-ray Evidence That the HIV Protease Catalytic Aspartyl Groups Are Protonated in the Complex Formed by the Protease and a Non-Peptide Cyclic Urea-Based Inhibitor
Nonstandard Amino Acids in Conformational Design of Peptides. Helical Structures in Crystals of 5-10 Residue Peptides Containing Dipropylglycine and Dibutylglycine
A New Chiral BLA Promoter for Asymmetric Aza Diels-Alder and Aldol-Type Reactions of Imines
Photoinduced Electron Transfer Reactions in Zeolite-Based Donor-Acceptor and Donor-Donor-Acceptor Diads and Triads
Quantification of Solvent Effects on the Acidities of Z and E Esters from Fluid Simulations
Open-Shell Analogs of Closed Shell Reaction Paths: the SRN2' case
Novel Keto-Enol Systems
Synthesis of endo-Cp2TaH2(BO2C6H4) and exo-Cp2TaH2(BO2C6H4): Regioisomers of the First Tantalum Boryl Complexes
Characterization of the P+Ln Ion Molecule Clusters of the First- and Second-Row Hydrides
Time-Resolved Solid-State REDOR NMR Measurements on 5-Enolpyruvylshikimate 3-Phosphate Synthase
Phosphine-Catalyzed Isomerization-Addition of Oxygen Nucleophiles to 2-Alkynoates
Interaction of Co.cntdot.Bleomycin A2 (Green) with d(CCAGGCCTGG)2: Evidence for Intercalation Using 2D NMR
Stereoregular Precursors to Poly(p-phenylene) via Transition-Metal-Catalyzed Polymerization. 1. Precursor Design and Synthesis
Synthetic Studies on the 1,6-Methano[10]annulene Skeleton: A New Route That Provides Derivatives Substituted at the Bridge and on the Annulene Ring
The Excited State Potential Energy Surface for the Photoisomerization of Tetraphenylethylene: A Fluorescence and Picosecond Optical Calorimetry Investigation
An Ab Initio Investigation of the Structure and Alkali Metal Cation Selectivity of 18-Crown-6
Silver Complexation by .sigma. C-H Bonds: Interaction of Silver with meso-Octaethyltetraoxaporphyrinogen
A Direct Measure of the Contribution of Solvent Reorganization to the Enthalpy of Binding
Investigation of Electronic Communication in Multi-Porphyrin Light-Harvesting Arrays
Reversal of Stereoselectivity in the Reduction of gem-Dichlorides by Tributyltin Hydride and Tris(trimethylsilyl)silane. Synthetic and Mechanistic Implications
Synthesis of (+)-Zaragozic Acid C
Valence-Bond Charge-Transfer Model for Nonlinear Optical Properties of Charge-Transfer Organic Molecules
Cyclic ADP-Ribose via Stereoselective Cyclization of .beta.-NAD
Catalytic Ring Closing Metathesis of Dienynes: Construction of Fused Bicyclic Rings
Stereochemistry of the Thermal Isomerization of Vinylcyclopropane to Cyclopentene
Effects of Mutations and Complex Formation on the Reduction Potentials of Cytochrome c and Cytochrome c Peroxidase
Photochemistry of Structurally-Modified Morphine Alkaloids
Channel-Mediated Transport of Glucose across Lipid Bilayers
Chemistry of 1,2-Dithiins. Synthesis of the Potent Antibiotic Thiarubrine A
CuA of Cytochrome c Oxidase and the A Site of N2O Reductase Are Tetrahedrally Distorted Type 1 Cu Cysteinates
AOT Reversed Micelles Investigated by Fluorescence Anisotropy of Cresyl Violet
Ab-Initio Calculation of the Charge Topology of the Oxygen Active Site of the (001) Surface of Pure and Doped MgO
Reactions of the Charged Radical (CH3)2S+-CH2.bul. with Cyclic Alkenes
Geminal Dialkyl Substitution, Intramolecular Reactions, and Enzyme Efficiency
Application of Old and New Values of .alpha.-Helix Propensities to the Helix-Coil Transition of Poly(L-glutamic acid)
Energy- and Electron-Transfer Processes Involving Palladium Porphyrins Bound to DNA
Stereochemical and Isotopic Labeling Studies of 4-Oxalocrotonate Decarboxylase and Vinylpyruvate Hydratase: Analysis and Mechanistic Implications
Stabilization of Carbanions. 1. Origin of the Increased Acidity of Dimethyl Sulfide As Compared to Dimethyl Ether
Selective Carbon-Carbon Bond Cleavage of Cyclopentadiene on a Trinuclear Ruthenium Pentahydride Complex
Synthesis of Sequence Specific Phenylacetylene Oligomers on an Insoluble Solid Support
Triplex Formation at Single-Stranded Nucleic Acid Target Sites of Unrestricted Sequence by Two Added Strands of Oligonucleotides: A Proposed Model
Mechanistic Origins of Acyloxydiazirines
Chiral Auxiliaries Promote both Diastereoselective Cycloaddition and Kinetic Resolution of Products in the Ortho Photocycloaddition of Double Bonds to Benzene Rings
Synergism of Calcium and Carbohydrate Binding to Mammalian Lectin
Cyclic Hexapeptides and Chimeric Peptides as Mimics of Tendamistat
Singlet State Cis,Trans Photoisomerization and Intersystem Crossing of 1-Arylpropenes
Ab Initio Study of Structures and Energetics of Small Copper-Selenium Clusters
Gas-Phase Chemistry of Pentacoordinate Silicon Hydride Ions
Ethoxyvinyllithium-HMPA. Surprising Regiochemistry in Aromatic Metalation
A Versatile Tandem Catalysis Procedure for the Preparation of Novel Amino Acids and Peptides
Solution Structure of a Zn(II).cntdot.Bleomycin A5-d(CGCTAGCG)2 Complex
Masthead
Disulfide Bond Assignment of .omega.-Agatoxins IVB and IVC: Discovery of a D-Serine Residue in .omega.-Agatoxin IVB
Electric Field Modulated Nonlinear Optical Properties of Donor-Acceptor Polyenes: Sum-Over-States Investigation of the Relationship between Molecular Polarizabilities (.alpha., .beta., and .gamma.) and Bond Length Alternation
Observation of a New Oxygen-Isotope-Sensitive Raman Band for Oxyhemoproteins and Its Implications in Heme Pocket Structures
Potential Energy Surfaces of the Gas-Phase SN2 Reactions X- + CH3X = XCH3 + X- (X = F, Cl, Br, I): A Comparative Study by Density Functional Theory and ab Initio Methods
Study of the Stability and Hydration of Doubly Charged Ions in the Gas Phase: SO42-, S2O62-, S2O82-, and Some Related Species
Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain
Temperature Dependence of the Energetics of Oligonucleotide-Directed Triple-Helix Formation at a Single DNA Site
Simulated Tribochemistry: An Atomic-Scale View of the Wear of Diamond
Amphiphilic nonlinear optical bis-chromophores and their mixtures with amphotropic copolymers: preparation of monolayers and Langmuir-Blodgett multilayers
Picosecond and Two-Step LIF Studies of the Excited-State Proton Transfer in 3-Hydroxyxanthone and 7-Hydroxyflavone Methanol Solutions: Reinvestigation of Tautomer and Anion Formations
trans-2,3-cis-3,4-Dihydroxyproline, a New Naturally Occurring Amino Acid, Is the Sixth Residue in the Tandemly Repeated Consensus Decapeptides of an Adhesive Protein from Mytilus edulis
First Observation of a n-Doped Quasi-One-Dimensional Electronically-Conducting Discotic Liquid Crystal
A Structurally Characterized Mononuclear Copper(II)-Superoxo Complex
In situ NMR Observation of a .pi.-Allylic Intermediate on Zinc Oxide Catalyst
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