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Ribonuclease Revisited: Catalysis via the Classical General Acid-Base Mechanism or a Triester-like Mechanism?
Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .beta.-Methoxy-.alpha.-nitrostilbene with CF3CH2O-
Formation of [BH3]2- and [B2H6]2- From the Homogeneous Reduction of B2H6
Molecular Tectonics. Three-Dimensional Organic Networks with Zeolitic Properties
Enantioselective Hydrosilylation of Ketones with a Chiral Titanocene Catalyst
Electronic spectral studies of molybdenyl complexes: implications for oxomolybdenum enzymes
Hydrates of Weak and Strong Bases. 12. 18-Crown-6 and Water: Crystal Structure of a Binary Hydrate.
Structural Effects in Novel Steroidal Polyamine-DNA Binding
Stepwise Hydrolysis of a Terminal Nitrosyl Ligand
Thioanisole Sulfoxidation by Cytochrome P450cam (CYP101): Experimental and Calculated Absolute Stereochemistries
Synthetic Control of Solid/Solid Interfaces: Analysis of Three New Silicon/Silicon Oxide Interfaces by Soft X-ray Photoemission
Accurate First Principles Calculation of Molecular Charge Distributions and Solvation Energies from Ab Initio Quantum Mechanics and Continuum Dielectric Theory
Kinetics of One-Electron Oxidation of Thiols and Hydrogen Abstraction by Thiyl Radicals from .alpha.-Amino C-H Bonds
Coenzyme-Amino Acid Chimeras: New Residues for the Assembly of Functional Proteins
D-term scattering in the resonance Raman spectrum of C60
Excited State Intramolecular Hydrogen Atom Transfer at Ultralow Temperatures. Evidence for Tunneling and Activated Mechanisms in 1,4-Dimethylanthrone
Living Polymerization of Phenylacetylenes Initiated by Rh(C.tplbond.CC6H5)(2,5-norbornadiene)[P(C6H5)3]2
A Role for Thr 252 in Cytochrome P450cam Oxygen Activation
Synthesis of Polysubstituted Indoles and Indolines by Means of Zirconocene-Stabilized Benzyne Complexes
Book Reviews
Characterization of the conductivity of organic thiols by field emission microscopy and field emission spectroscopy
Verdoheme-like Oxaporphyrin Formation by Oxygenation of a Co(II) Porphyrinyl Naphthoic Acid. A New Model of Heme Degradation
"Redox Tautomerism" in High-Valent Metal-oxo-aquo Complexes. Origin of the Oxygen Atom in Epoxidation Reactions Catalyzed by Water-Soluble Metalloporphyrins. [Erratum to document cited in CA122:105083]
Photoinduced Wolff-Rearrangement of 2-Diazo-1-naphthoquinones: Evidence for the Participation of a Carbene Intermediate
Matrix-Isolation and ab Initio Molecular Orbital Study of 2,2,2-Trifluoroethylidene
Enantioselective Adsorption of the D- and L-Forms of an .alpha.-Helical Antifreeze Polypeptide to the {20.hivin.21} Planes of Ice
Precision Sequence-Specific Cleavage of a Nucleic Acid by a Minor-Groove-Directed Metal-Binding Ligand Linked through N-2 of Deoxyguanosine
Catalysis of an Intramolecular Aldol Condensation by Imidazole-Bearing Cyclodextrins
Highly Enantioselective, Low-Temperature Epoxidation of Styrene. [Erratum to document cited in CA122:55828]
Synthesis and Postsynthetic Modification of Oligodeoxynucleotides Containing 4-Thio-2'-deoxyuridine (ds4U)
Experimental Enthalpies of Formation and Strain Energies for the Caged C20H20 Pagodane and Dodecahedrane Frameworks
Spectroscopic Studies of Protonated Aromatic Species and Radical Cations in H+-Zeolites
Totally Selective NN Bond Cleavage in the Dissociative Adsorption of Diazirine on Cu(110)
Solid-State 13C NMR Evidence for a Large Deviation from Linearity of the Fe-C-O Unit in the CO Complex with Myoglobin
Photoinduced Electron-Transfer Reactions of Aryl Olefins. 1. Investigation of the Paterno-Buechi Reaction between Quinones and Anetholes in Polar Solvents
Imine-Bridged Planar Poly(p-phenylene) Derivatives for Maximization of Extended .pi.-Conjugation. The Common Intermediate Approach
Addition of tert-Butyl Radical to Substituted Alkenes: A Theoretical Study of the Reaction Mechanism
2'-Ribose Substituent Effects on the Chemical and Enzymic Hydrolysis of NAD+
Kinetic Resolution of 1,2-Dihydronaphthalene Oxide and Related Epoxides via Asymmetric C-H Hydroxylation
A CPMAS 13C NMR Study of Molecular Conformations and Disorder of N-Octylhexonamides in Microcrystals and Supramolecular Assemblies
A Monomeric Solvent-Free Bent Lanthanide Dialkyl and a Lanthanide Analog of a Grignard Reagent. Crystal Structures of Yb{C(SiMe3)3}2 and [Yb{C(SiMe3)3}I.cntdot.OEt2]2
First Example of a Highly Enantioselective Catalytic Diels-Alder Reaction of an Achiral C2v-Symmetric Dienophile and an Achiral Diene
Living Anionic Ring-Opening Polymerization of Silicon-Bridged [1]Ferrocenophanes: Synthesis and Characterization of Poly(ferrocenylsilane)-Polysiloxane Block Copolymers
310 Helix Versus .alpha.-Helix: A Molecular Dynamics Study of Conformational Preferences of Aib and Alanine
Molecular Dynamics and Magic Angle Spinning NMR
Differential Side Chain Hydration in a Linear Peptide Containing a Type VI Turn
Mechanism-Based Inactivation of Glutathione Synthetase by Phosphinic Acid Transition-State Analog
Orthogonal Glycosylation Strategy in Oligosaccharide Synthesis
Charge-Transfer Complexes Acting as Real Intermediates in Hydride Transfer from Michler's Hydride to 2,3-Dichloro-5,6-dicyano-p-benzoquinone via Electron Transfer
Arenediazonium Salts: New Probes of the Interfacial Compositions of Association Colloids. 3. Distributions of Butanol, Hexanol, and Water in Four-Component Cationic Microemulsions
Spin Frustration in High-Spin Triiron(III) Complexes: An Inelastic Neutron Scattering Study
Spontaneous Loss of Molecular Hydrogen from Tungsten(IV) Alkyl Complexes To Give Alkylidyne Complexes
Asymmetric Synthesis of an HIV Protease Inhibitor via a Novel .alpha.-Oxoketene/Ketene [4 + 2] Cycloaddition Reaction
Masthead
A General Acid-Catalyzed Anion Breakdown Associated with an E1cB Reaction in the Hydrolysis of Aryl N-(Substituted Phenylsulfonyl)carbamates
Ligand Binding to Four-Atom-Linked Capped Porphyrins
Poly(silaethylene): A Novel Analog of Polyethylene
Migration Versus Insertion in Square-Planar Platinum and Palladium Complexes
A Suite of Triple Resonance NMR Experiments for the Backbone Assignment of 15N, 13C, 2H Labeled Proteins with High Sensitivity
.pi.-Facial Selectivity in Nucleophilic Additions to 4,4-Disubstituted Dienones: Experimental Support for Electrostatic Control
Oligosiloles: First Synthesis Based on a Novel Endo-Endo Mode Intramolecular Reductive Cyclization of Diethynylsilanes
The Active Site of Hydroxylamine Oxidoreductase from Nitrosomonas: Evidence for a New Metal Cluster in Enzymes
Aristolochene Synthase. Mechanism-Based Inhibition of a Terpenoid Cyclase
Construction and Characterization of Hybrid Component 1 from V-Nitrogenase Containing FeMo Cofactor
Asymmetric Synthesis of the Squalene Synthase Inhibitor Zaragozic Acid C
Kinetic Isotope Effects on Ethyl Metaphosphate Transfer from a Phosphoramidate to Ethanol
Water Exchange Filter (WEX Filter) for Nuclear Magnetic Resonance Studies of Macromolecules
High-Stability Liposomes from Macrocyclic Diyne Phospholipids
Effect of .alpha.-Carbomethoxy Group on the Reactivity of Benzyl Cations in Solution
Structure-Reactivity Relationship in Oxygen and Carbon Monoxide Binding with Some Heme Models
A Synchrotron X-ray Diffraction, Neutron Diffraction, 29Si MAS-NMR, and Computational Study of the Siliceous Form of Zeolite Ferrierite
Density Functional/Poisson-Boltzmann Calculations of Redox Potentials for Iron-Sulfur Clusters
Formation and Reactions of Bicyclo[1.1.1]pentyl-1 Cations
Computational Simulations of Supramolecular Hydrogen-Bonded Aggregates: HubM3, FlexM3, and Adamantane-Based Hubs in Chloroform
Formation of Charge Relay Chains between Acetic Acid and Pyridine Observed by Low-Temperature Nuclear Magnetic Resonance
Planar Tetracoordinate Carbons in Dimetallic Complexes: Quantum Chemical Investigations. [Erratum to document cited in CA121:179786]
Effects of Solvents and Additives in the Asymmetric Heck Reaction of Alkenyl Triflates: Catalytic Asymmetric Synthesis of Decalin Derivatives and Determination of the Absolute Stereochemistry of (+)-Vernolepin
Gas-Phase Properties and Reactivity of the Acetate Radical Anion. Determination of the C-H Bond Strengths in Acetic Acid and Acetate Ion
Cis-Trans Imide Isomerization of the Proline Dipeptide
Optically Active Polysilane Homopolymer: Spectroscopic Evidence of Double-Screw-Sense Helical Segmentation and Reconstruction of a Single-Screw-Sense Helix by the "Cut-and-Paste" Technique
Ab Initio Quality Electron Densities for Proteins: A MEDLA Approach
Total Synthesis of 3'-O-Sialyl, 6'-O-Sulfo Lewisx, NeuAc.alpha.2.fwdarw.3(6-O-SO3Na)Ga1.beta.1.fwdarw.4(Fuc.alpha.1.fwdarw.3)GlcNAc.beta.-OMe: A Major Capping Group of GLYCAM-I
A Practical, General Three-Component Coupling Approach to Prostaglandin and Non-Prostaglandin-Related Skeleta
Transition Structures and Kinetic Isotope Effects for the Claisen Rearrangement
Spin-Orbit Coupling-Induced Electron Spin Polarization Observed in Photosensitized Electron Transfer Reactions between Xanthene Dyes and p-Quinones
Coordination Chemistry on Surfaces: A New Method To Graft Rhenium(VII) Oxide on Highly Dehydroxylated Oxides
A Monomeric Side-On Superoxocopper(II) Complex: Cu(O2)(HB(3-tBu-5-iPrpz)3)
Autopoietic Self-Reproduction of Fatty Acid Vesicles
Catalytic Asymmetric Hydrogenation of Imines with a Chiral Titanocene Catalyst: Kinetic and Mechanistic Investigations
Conformational Dynamics of Calixarenes. Kinetics of Conformational Interconversion in 5,11,17,23-Tetra-p-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene under Entropic Control
9,10-Bis(spirocyclopropyl)-9,10-dihydroanthracenes: Sterically Induced Deep Conformational Energy Wells
Synthesis of Cell Agglutination Inhibitors by Aqueous Ring-Opening Metathesis Polymerization
Accurate Solvation Free Energies of Acetate and Methylammonium Ions Calculated with a Polarizable Water Model
Short Enantioselective Synthesis of (-)-Ovalicin, a Potent Inhibitor of Angiogenesis, Using Substrate-Enhanced Catalytic Asymmetric Dihydroxylation
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