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Novel Metal−Carbon Multiply BondedTwelve-Electron Complexes of Ti and Zr Supportedby a Bis(Phosphoranimine) Chelate
Why Does the Reaction of the Dihydrogen Molecule with[P2N2]Zr(μ-η2-N2)Zr[P2N2] Produce [P2N2]Zr(μ-η2-N2H)Zr[P2N2](μ-H)but Not the Thermodynamically More Favorable[P2N2]Zr(μ-NH)2Zr[P2N2]? A Theoretical Study
First Iminodiazaphospholidines with a StereogenicPhosphorus Center. Application to AsymmetricCopper-Catalyzed Cyclopropanation
Highly Stereospecific, Cross-Coupling Reactions ofAlkenylsilacyclobutanes
Discrimination of Rotamers of Aryl Alcohol Homologues byInfrared−Ultraviolet Double-Resonance Spectroscopy in a SupersonicJet
Nickel on Charcoal (“Ni/C”): An Expedient andInexpensive Heterogeneous Catalyst forCross-Couplings between Aryl Chlorides andOrganometallics. I. Functionalized OrganozincReagents
Mechanism of Photosolvolytic Rearrangement of p-HydroxyphenacylEsters: Evidence for Excited-State Intramolecular Proton Transfer asthe Primary Photochemical Step
Structure and Total Synthesis of HF-7, a Neuroactive GlyconucleosideDisulfate from the Funnel-Web Spider Hololena curta
Enantiocontrolled [5 + 2] Cycloaddition toη3-Pyranylmolybdenum π-Complexes. Synthesis ofSubstituted Oxabicyclo[3.2.1]octenes of HighEnantiopurity
A Potent Transition-State Analogue Inhibitor ofEscherichia coli Asparagine Synthetase A
Synthesis of Group 4 Complexes that Contain theDiamidoamine Ligands,[(2,4,6-Me3C6H2NCH2CH2)2NR]2- ([Mes2N2NR]2-; R= H or CH3), and Polymerization of 1-Hexene byActivated [Mes2N2NR]ZrMe2 Complexes
X-ray Analysis of Structural Changes inPhotochromic Salicylideneaniline Crystals.Solid-State Reaction Induced by Two-PhotonExcitation
Role of l-3,4-Dihydroxyphenylalanine in MusselAdhesive Proteins
Effect of Protein Microenvironment on Tyrosyl Radicals. AHigh-Field (285 GHz) EPR, Resonance Raman, and Hybrid DensityFunctional Study
Vapor-Phase Photochemistry of Dimethylpyridines
Theoretical Study of Base-Catalyzed Amide Hydrolysis: Gas- andAqueous-Phase Hydrolysis of Formamide
Cascade of Molecular Order by SequentialSelf-Organization, Induced Orientation, and OrderTransfer Processes
2-Aryl-4,4,8-trimethyl-2-phosphabicyclo[3.3.0]octanes: Reactive Chiral Phosphine Catalysts forEnantioselective Acylation
An Asymmetric Aldol−Ring-Closing Metathesis Strategy for theEnantioselective Construction of Oxygen Heterocycles: An EfficientApproach to the Enantioselective Synthesis of (+)-Laurencin
A Simple Electrostatic Model for Trisilylamine: TheoreticalExaminations of the n→σ* Negative Hyperconjugation, pπ→dπBonding, and Stereoelectronic Interaction
Palladium-Catalyzed Cocyclization of Arynes withAlkynes: Selective Synthesis of Phenanthrenes andNaphthalenes
Novel Para-Substituted Benzyl Ethers for HydroxylGroup Protection
A Self-Destroying Polycationic Polymer: BiodegradablePoly(4-hydroxy-l-proline ester)
Efficient Synthesis of Purines and Purine Nucleosidesvia an Inverse Electron Demand Diels−AlderReaction
myo-Inositol 1-Phosphate Synthase: Does a SingleActive-Site Amino Acid Catalyze Multiple ProtonTransfers?
11,12-Difluororhodopsin and Related Odd-NumberedFluororhodopsins. The Use of JF,F for Following aCis−trans Isomerization Process
Role of the Terminal Atoms in the Donor−Acceptor ComplexesMX3−D (M = Al, Ga, In; X = F, Cl, Br, I; D = YH3, YX3, X-; Y= N, P, As)
Biomimetic Modeling of the First Substrate Reactionat the Active Site of Ribonucleotide Reductases.Abstraction of H3‘ by a Thiyl Free Radical1
Catalysis for Catalysis: Synthesis of MixedPhosphine−Phosphine Oxide Ligands via HighlySelective, Pd-Catalyzed Monooxidation of BidentatePhosphines
Biosynthesis of Phenazine Antibiotics in Streptomyces antibioticus: Stereochemistry of Methyl Transfer from Carbon-2 of Acetate
Ground- and Excited-State Reactions of Norbornene and Isomers:A CASSCF Study and Comparison with Femtosecond Experiments
Structure, Mobility, and Interface Characterization of Self-OrganizedOrganic−Inorganic Hybrid Materials by Solid-State NMR
Deuterium-MAS NMR Spectroscopy on Oriented MembraneProteins: Applications to Photointermediates of Bacteriorhodopsin
Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: TheEffect of Catalyst Activation Protocol and Additives on the ReactionRate and Enantioselectivity
Derivation of the Bound-State Conformation of aLigand in a Weakly Aligned Ligand−ProteinComplex
Thermodynamics of C−H Activation in Multiple Oxidation States: Comparison of Benzylic C−H Acidities and C−H Bond DissociationEnergies in the Isostructural 16−20-Electron Complexes[Fex(η5-C5R5)(η6-arene)]n, x = 0−IV, R = H or Me, n = −1 to +3
Hot Spot Conditions during Cavitation in Water
Binding-Induced Activation of DNA Alkylation by Duocarmycin SA: Insights from the Structure of an Indole Derivative−DNA Adduct
Toward a Consistent Mechanism for Diol Dehydratase CatalyzedReactions: An Application of the Partial-Proton-Transfer Concept
A Rationally Designed Inhibitor ofα-1,3-Galactosyltransferase
NMR, Relaxometric, and Structural Studies of the Hydration andExchange Dynamics of Cationic Lanthanide Complexes ofMacrocyclic Tetraamide Ligands
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