About: Asymmetric Synthesis of syn- and anti-1,3-Amino Alcohols

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_23/w
Subject	Communication
Title	Asymmetric Synthesis of syn- and anti-1,3-Amino Alcohols
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_23/101021ja026292g/m/print http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_23/101021ja026292g/m/web
related by	http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_23/101021ja026292g/authorship/3 http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_23/101021ja026292g/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_23/101021ja026292g/authorship/2
Author	Ellman Jonathan A. Kochi Takuya Tang Tony P.
Abstract	The first application of metalloenamines derived from N-sulfinyl imines is reported for the highly diastereoselective addition to aldehydes. Reduction of the β-hydroxy-N-sulfinyl imine products with catecholborane and LiBHEt3 provides syn- and anti-1,3-amino alcohol derivatives, respectively, with very high diastereomeric ratios.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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