About: An Unprecedented Dinuclear Alkylrhodium(III) Complex Built up by Two14-Electron [RhCl2(alkyl)(PR3)] Units

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_33/w
Subject	Communication
Title	An Unprecedented Dinuclear Alkylrhodium(III) Complex Built up by Two14-Electron [RhCl2(alkyl)(PR3)] Units
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_33/101021ja020560t/m/web http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_33/101021ja020560t/m/print
related by	http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_33/101021ja020560t/authorship/3 http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_33/101021ja020560t/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2002/volume_124/issue_33/101021ja020560t/authorship/2
Author	Brandt Carsten D. Werner Helmut Canepa Giuseppe
Abstract	Reaction of HCl with [RhCl(C2H4)(PR3)]2 affords the dinuclear alkylrhodium(III) complex [RhCl2(C2H5)(PR3)]2, the structure of which has been determined crystallographically. PR3 is the formerly unknown trialkyl phosphine tBu2PCH2CH2C6H3-2,6-Me2, prepared in three steps from tBuPCl2. Treatment of the title compound with CO gives the mononuclear rhodium dicarbonyl cis-[RhCl(CO)2(PR3)], being the first fully characterized complex of this type.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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