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À propos de : Synthesis and Structure of the First 1,2σ5-Selenaphosphirane        

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  • Synthesis and Structure of the First 1,2σ5-Selenaphosphirane
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  • A 1,2σ5-selenaphosphirane bearing the Martin ligand was synthesized. Its structure in both the solid and the solution state was established by X-ray crystallographic analysis and NMR measurements, respectively. The selenaphosphirane has a polar P−Se bond, and the selenium atom is negatively charged. In the solution state, the degree of polarization of the P−Se bond depends on the acceptor number of the solvents.
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