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À propos de : Anion−Anion Assembly: A New Class of Anionic Supramolecular PolymerContaining 3,4-Dichloro-2,5-diamido-substituted Pyrrole Anion Dimers        

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  • Anion−Anion Assembly: A New Class of Anionic Supramolecular PolymerContaining 3,4-Dichloro-2,5-diamido-substituted Pyrrole Anion Dimers
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  • Two molecules containing two 2,5-diamido,3,4-dichloropyrrole units linked via 1,3- or 1,4-substituted benzene rings have been synthesized. The pyrrole groups in these compounds deprotonate in the presence of tetrabutylammonium fluoride and form pyrrole anion dimers via NH···N- hydrogen bonds. This dimerization process results in the formation of polyanionic chains linked via an unusual “orthogonal” hydrogen-bonding array.
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