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À propos de : σσ* Transition in anti,cisoid Alternating Oligosilanes: Clear-Cut Evidence forSuppression of Conjugation Effect by a cisoid Turn        

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  • σσ* Transition in anti,cisoid Alternating Oligosilanes: Clear-Cut Evidence forSuppression of Conjugation Effect by a cisoid Turn
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  • On the basis of the UV absorption spectra of the anti,cisoid alternating oligosilanes, the first experimental clear-cut evidence was presented for the generally accepted idea that the σ conjugation in polysilanes does not effectively extend through a tetrasilane fragment with a small dihedral angle such as a cisoid turn.
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