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À propos de : A Reversible Valence Equilibrium in a Heavier Main Group Compound        

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  • A Reversible Valence Equilibrium in a Heavier Main Group Compound
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  • The addition of LiPh to Ar*SnCl (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-iPr3) at low temperature afforded the Sn(1)−Sn(III) species Ar*SnSnPh2Ar*, which exists in equilibrium with the Sn(II) compound Ar*SnPh. It is the first example of a room-temperature equilibrium of compounds involving main group elements in different oxidation states.
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