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À propos de : Control of Chiral Ordering in AggregatedPoly{3-(S)-[2-methylbutyl]thiophene} by a Doping-DedopingProcess        

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  • Control of Chiral Ordering in AggregatedPoly{3-(S)-[2-methylbutyl]thiophene} by a Doping-DedopingProcess
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  • The chiral ordering in aggregated poly(3-alkylthiophene) can be controlled by a metal salt-dependent doping-dedoping process. Enhancement or reduction in the chiral anisotropy factor dependson the doping level, such that doping driven by polymer−metal salt interactions, and dedoping driven byaggregate formation must be balanced in order to achieve maximal chiral ordering. This phenomenonprovides a new basis to control chiral arrangement in conjugated polymer aggregates, relying solely ondoping, and thus avoiding tedious modification of side-chain or main-chain structures.
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