About: One Ligand Fits All: Cationic Mono(amidinate) Alkyl Catalysts over the FullSize Range of the Group 3 and Lanthanide Metals

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_30/w
Subject	Communication
Title	One Ligand Fits All: Cationic Mono(amidinate) Alkyl Catalysts over the FullSize Range of the Group 3 and Lanthanide Metals
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_30/101021ja0475297/m/print http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_30/101021ja0475297/m/web
related by	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_30/101021ja0475297/authorship/2 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_30/101021ja0475297/authorship/3 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_30/101021ja0475297/authorship/4 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_30/101021ja0475297/authorship/1
Author	Meetsma Auke Bouwkamp Marco W. Bambirra Sergio Hessen Bart
Abstract	Using a sterically demanding amidinate ancillary ligand and an in situ alkylation procedure, neutral mono(amidinate) dialkyl and cationic mono(amidinate) monoalkyl complexes were prepared for metals spanning the full size range of the group 3 and lanthanide metals. The activity of the cationic monoalkyls in catalytic ethene polymerization was found to vary by over 2 orders of magnitude depending on the metal ionic radius, the intermediate metal sizes being found to be the most effective.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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