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À propos de : Biaryl Synthesis via Direct Arylation: Establishment of an Efficient Catalystfor Intramolecular Processes        

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  • Biaryl Synthesis via Direct Arylation: Establishment of an Efficient Catalystfor Intramolecular Processes
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  • In this Communication, we describe direct arylation reactions with improved scope and catalyst activity for the intramolecular formation of biaryl compounds. This was achieved through the establishment of a highly active and robust catalyst system and the subsequent development of a novel phosphine ligand 27. The enhanced catalytic activity extends these transformations to include previously unreactive and poorly reactive substrates, and allows for very low catalyst loadings to be employedas little as 0.1 mol %.
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