About: Synthesis and Reactivity of Dimethyl Platinum(IV) Hydrides in Water

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_36/w
Subject	Communication
Title	Synthesis and Reactivity of Dimethyl Platinum(IV) Hydrides in Water
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_36/101021ja046310p/m/print http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_36/101021ja046310p/m/web
related by	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_36/101021ja046310p/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_36/101021ja046310p/authorship/3 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_36/101021ja046310p/authorship/2
Author	Vedernikov Andrei N. Fettinger James C. Mohr Fabian
Abstract	New hydrophilic ligands of the di(2-pyridyl)methanesulfonate family, L = dpms and Me-dpms, enable the synthesis of methyl platinum(IV) hydrides, LPtMe2H, the study of very fast CH reductive coupling, and reductive elimination of these complexes in water. In dichloromethane solutions, 13CH4 reacts with (Me-dpms)PtMe2H to produce isotopomeric complexes.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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