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Alkenes from Terminal Epoxides Using Lithium 2,2,6,6-Tetramethylpiperidideand Organolithiums or Grignard Reagents
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http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/w
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Title
Alkenes from Terminal Epoxides Using Lithium 2,2,6,6-Tetramethylpiperidideand Organolithiums or Grignard Reagents
has manifestation of work
http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja045513a/m/print
http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja045513a/m/web
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http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja045513a/authorship/1
http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja045513a/authorship/2
http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja045513a/authorship/3
Author
Fleming Matthew J.
Stanway Steven J.
Hodgson David M.
Abstract
E-Alkenes (including arylated alkenes, dienes, and allylsilanes) are efficiently prepared by α-deprotonation of terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide, followed by in situ trapping with organolithiums or Grignard reagents.
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Journal of the American Chemical Society
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