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À propos de : Palladium-Catalyzed Copolymerization of Ethene with Acrolein DimethylAcetal: Catalyst Action and Deactivation        

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  • Palladium-Catalyzed Copolymerization of Ethene with Acrolein DimethylAcetal: Catalyst Action and Deactivation
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  • Acrolein dimethyl acetal (ADMA) can be copolymerized with ethene using a cationic α-diimine palladium chelate catalyst to yield branched copolymers. Catalyst deactivation occurs via methanol elimination to give an inert η3-1-methoxyallyl palladium species. This process can be retarded by the addition of an aliquot of methanol to the reaction mixture, increasing overall catalyst productivity.
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