About: Fluoride-Facilitated Deuterium Exchange from DMSO-d6 to Polyamide-BasedCryptands

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/w
Subject	Communication
Title	Fluoride-Facilitated Deuterium Exchange from DMSO-d6 to Polyamide-BasedCryptands
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja046078n/m/print http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja046078n/m/web
related by	http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja046078n/authorship/3 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja046078n/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja046078n/authorship/2 http://hub.abes.fr/acs/periodical/jacsat/2004/volume_126/issue_39/101021ja046078n/authorship/4
Author	Kang Sung Ok Powell Douglas Bowman-James Kristin VanderVelde David
Abstract	Multiple deuterium exchange between DMSO-d6 and amide hydrogens in two hexaamido cryptand fluoride receptors has been verified by 19F and 2H NMR and FAB mass spectral studies. Structural results for one of the complexes indicate a tricapped trigonal prism hydrogen bond coordination geometry around an encapsulated fluoride, with hydrogen bonds from fluoride to six amide and three phenyl hydrogens.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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