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Synthesis and Derivatization of Daptomycin: AChemoenzymatic Route to Acidic Lipopeptide Antibiotics
Stereoselectivity Control by Oxaspiro Rings duringDiels−Alder Cycloadditions to Cross-ConjugatedCyclohexadienones: The Syn Oxygen Phenomenon
Acyclic Telluroiminium Salts: Isolation and Characterization
Cavity-Induced Spin−Spin Interaction between Organic Radicals within aSelf-Assembled Coordination Cage
Enantioselective Synthesis of Six-Membered PalladacyclesHaving Metal-Bound Stereogenic Carbons: Isolation andReactivity of Palladacycles Containing Readily Accessibleβ-Hydrogens
Automatic and Subsequent Dissolution and Precipitation Process inInorganic Macroionic Solutions
Laser Tweezers Raman Study of Optically Trapped Aerosol Droplets ofSeawater and Oleic Acid Reacting with Ozone: Implications forCloud-Droplet Properties
Zirconium Sandwich Complexes with η9 Indenyl Ligands: Well-Defined Precursors for Zirconocene-MediatedCoupling Reactions
Nanocrystalline Iron Oxide Aerogels as Mesoporous MagneticArchitectures
Stability of Polypeptide Multilayers As Studied by in SituEllipsometry: Effects of Drying and Post-Buildup Changes inTemperature and pH
Synthesis and Properties of Highly FluorescentIndolizino[3,4,5-ab]isoindoles
Light-Directed Radial Combinatorial Chemistry: Orthogonal Safety-CatchProtecting Groups for the Synthesis of Small Molecule Microarrays
Specific Radiation Damage Illustrates Light-Induced Structural Changes inthe Photosynthetic Reaction Center
pH-Triggered Assembly of Organometallic Receptors forLithium Ions
Toward Assessing the Position-Dependent Contributions ofBackbone Hydrogen Bonding to β-Sheet FoldingThermodynamics Employing Amide-to-Ester Perturbations
Temperature-Dependent Behavior of a Symmetric Long-ChainBolaamphiphile with Phosphocholine Headgroups in Water: From Hydrogel to Nanoparticles
Electrochemical and Conductivity Measurements of Single-Wall CarbonNanotube Network Electrodes
Preparation and Characterization of the NativeIron(II)-Containing DNA Repair AlkB Protein Directly fromEscherichia coli
Diphosphine−Phosphenium Coordination ComplexesRepresenting Monocations with Pendant Donors and LigandTethered Dications
Direct Imaging of Zero-Field Dipolar Structures in Colloidal Dispersions ofSynthetic Magnetite
Formation of the Aureothin Tetrahydrofuran Ring by a BifunctionalCytochrome P450 Monooxygenase
Vapochromism and Its Structural Basis in a LuminescentPt(II) Terpyridine−Nicotinamide Complex
Large-Scale Fabrication of Aligned Single-Walled Carbon Nanotube Array andHierarchical Single-Walled Carbon Nanotube Assembly
The Mobile Proton in Polyalanine Peptides
Isoxazolyl-Serine-Based Agonists of Peroxisome Proliferator-ActivatedReceptor: Design, Synthesis, and Effects on Cardiomyocyte Differentiation
Perturbation of Fluorescence by Nonspecific Interactionsbetween Anionic Poly(phenylenevinylene)s and Proteins: Implications for Biosensors
Fabrication of ZnO “Dandelions” via a Modified Kirkendall Process
Stepwise and Concerted Electron-Transfer/Bond BreakingReactions. Solvent Control of the Existence of Unstable π IonRadicals and of the Activation Barriers of Their HeterolyticCleavage
Threading-Followed-by-Shrinking Protocol for the Synthesis of a [2]RotaxaneIncorporating a Pd(II)−Salophen Moiety
Characterization of 5-Hydroxy-8-oxo-7,8-dihydroguanosine inthe Photosensitized Oxidation of 8-Oxo-7,8-dihydroguanosineand Its Rearrangement to Spiroiminodihydantoin
Self-Metallization of Photocatalytic Porphyrin Nanotubes
Electronic Effects Steer the Mechanism of Asymmetric Hydrogenations ofUnfunctionalized Aryl-Substituted Alkenes
Predictive in Silico All-Atom Folding of a Four-Helix Protein with aFree-Energy Model
Dioxygen Activation at a Single Copper Site: Structure,Bonding, and Mechanism of Formation of 1:1 Cu−O2 Adducts
Self-Assembled Monolayers of Cobalt(II)−(4-tert-Butylphenyl)-Porphyrins: The Influence of theElectronic Dipole on Scanning Tunneling Microscopy Images
Characterization of tylM3/tylM2 and mydC/mycB Pairs Required for EfficientGlycosyltransfer in Macrolide Antibiotic Biosynthesis
Sequence and Structural Duality: Designing Peptides toAdopt Two Stable Conformations
Water-Dependent Reactions of Diiron(II) Carboxylate Complexes
c-di-GMP Displays A Monovalent Metal Ion-Dependent Polymorphism
Electron Transfer at a Dithiolate-Bridged Diiron Assembly: Electrocatalytic Hydrogen Evolution
Brownian Force Profile Reconstruction of Interfacial1-Nonanol Solvent Structure
Density Functional Theory Studies on the Mechanisms ofRegioselective Allylic and cis-Vinylic Deprotonation of AllylAmides and Allylamines
Site-Specific Replacement of a Conserved Tyrosine in RibonucleotideReductase with an Aniline Amino Acid: A Mechanistic Probe for aRedox-Active Tyrosine
Dispersion and Current−Voltage Characteristics of Helical PolyacetyleneSingle Fibers
XeAuF
Ligand K-edge X-ray Absorption Spectroscopy and DFTCalculations on [Fe3S4]0,+ Clusters: Delocalization, Redox,and Effect of the Protein Environment
Role of the Orbitally Degenerate Mn(III) Ions in theSingle-Molecule Magnet Behavior of the Cyanide Cluster{[MnII(tmphen)2]3[MnIII(CN)6]2}(tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline)
Formation and Manipulation of Protopolymer Chains
Effect of a Weak Magnetic Field on the Reaction between Neutral FreeRadicals in Isotropic Solution
A Sterically Expanded “Constrained Geometry Catalyst” for Highly ActiveOlefin Polymerization and Copolymerization: An Unyielding ComonomerEffect
A DFT Computational Study on Electrophilic Substitutions uponα-Oxy-Substituted Benzylorganolithium Compounds: Lithium Catalysis Is theHidden Piece of the Puzzle
Hydrogen Bonds of RNA Are Stronger than Those of DNA, but NMR MonitorsOnly Presence of Methyl Substituent in Uracil/Thymine
A Family of Decamethylmetallocene Charge-Transfer SaltMagnets Using Methyl Tricyanoethylenecarboxylate (MTCE)as the Electron Acceptor
Photochemistry of Artificial Photosynthetic Reaction Centersin Liquid Crystals Probed by Multifrequency EPR(9.5 and 95 GHz)
Dehydrogenation versus Oxygenation in Two-Electron andFour-Electron Reduction of Dioxygen by9-Alkyl-10-methyl-9,10-dihydroacridines Catalyzed byMonomeric Cobalt Porphyrins and Cofacial DicobaltPorphyrins in the Presence of Perchloric Acid
Structure−Property Correlations in Polypropylene fromMetallocene Catalysts: Stereodefective, RegioregularIsotactic Polypropylene
Structure-Based Design of Potent, Conformationally Constrained SmacMimetics
Engineering the Reactivity of Metal Catalysts: A Model Study of MethaneDehydrogenation on Rh(111)
Assembly of a Supramolecular Capsule on a MolecularPrintboard
Determination of the Chromophore Structures in the Photoinduced ReactionCycle of Phytochrome
Superbowl Container Molecules
Detection and Reactivity of Pd((C8H14)PCH2CH2P(C8H14))(CHPhCH2Ph)(H) asDetermined by Parahydrogen-Enhanced NMR Spectroscopy
Efficient Photodissociation of O2 from Synthetic Heme and Heme/M(M = Fe, Cu) Complexes
Tetra-Rhenium Molecular Rectangles as Organizational Motifsfor the Investigation of Ligand-Centered Mixed Valency: Three Examples of Full Delocalization
Dissociation of Carbanions from Acyl Iridium Compounds: An Experimental and Computational Investigation
Structural Insights into Nonheme Alkylperoxoiron(III) andOxoiron(IV) Intermediates by X-ray Absorption Spectroscopy
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