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À propos de : Synthesis of Aryl Ketones by the Pd-Catalyzed C−H Activation of Arenes andIntermolecular Carbopalladation of Nitriles        

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  • Synthesis of Aryl Ketones by the Pd-Catalyzed C−H Activation of Arenes andIntermolecular Carbopalladation of Nitriles
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  • The palladium-catalyzed reaction of simple arenes and nitriles provides good to excellent yields of aryl ketones or the corresponding hindered imines. The addition of a small amount of DMSO increases the yields dramatically. Both intermolecular and intramolecular examples of this process are successful. This novel chemistry is believed to involve palladium-catalyzed C−H activation, followed by carbopalladation of the nitrile.
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