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An Expeditious Total Synthesis of (±)-Stenine
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http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_45/w
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Title
An Expeditious Total Synthesis of (±)-Stenine
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http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_45/101021ja055629m/m/web
http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_45/101021ja055629m/m/print
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http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_45/101021ja055629m/authorship/1
http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_45/101021ja055629m/authorship/2
Author
Aubé, Jeffrey
Zeng Yibin
Abstract
(±)-Stenine was synthesized in eight steps from a known ketophosphonate reagent. The key step was an exo-selective Diels−Alder/intramolecular Schmidt domino reaction that afforded three of the four rings and four stereocenters in a single reaction.
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Journal of the American Chemical Society
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