About: Catalytic Enantioselective Conia-Ene Reaction

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_49/w
Subject	Communication
Title	Catalytic Enantioselective Conia-Ene Reaction
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_49/101021ja055059q/m/print http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_49/101021ja055059q/m/web
related by	http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_49/101021ja055059q/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_49/101021ja055059q/authorship/2
Author	Corkey Britton K. Toste F. Dean
Abstract	An enantioselective intramolecular Conia-ene reaction of β-dicarbonyl compounds and alkynes to afford methylene cyclopentanes is described. The reaction employs a DTBMSegphos-Pd(II)/Yb(III) dual catalyst system that allows for the asymmetric synthesis of all-carbon quaternary centers and generates a product containing an alkene that can be further manipulated.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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