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À propos de : Unprecedented Chemistry of an Aryloxychlorodiazirine: Generation of aDihalodiazirine and Diazirinone        

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  • Unprecedented Chemistry of an Aryloxychlorodiazirine: Generation of aDihalodiazirine and Diazirinone
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  • The reaction of p-nitrophenoxychlorodiazirine with tetrabutylammonium fluoride follows three channels: (1) ∼17% of p-nitrophenoxide/fluoride exchange to chlorofluorodiazirine and p-nitrophenol, (2) ∼28% of Cl/F exchange to p-nitrophenoxyfluorodiazirine, and (3) ∼55% of ipso fluoride attack, affording p-nitrofluorobenzene and the previously unknown diazirinone (diazacyclopropenone).
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