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À propos de : Synthesis and Structure of a Stable Pentavalent-Uranyl Coordination Polymer        

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  • Synthesis and Structure of a Stable Pentavalent-Uranyl Coordination Polymer
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  • The polymeric complex {[UO2Py5][KI2Py2]}n was isolated by controlled oxidation of uranium tris-iodide in pyridine and structurally characterized using X-ray diffraction. The described synthetic method allows us to isolate a stable derivative of the elusive pentavalent UO2+ species providing a potential starting material for the development of anhydrous UO2+ coordination chemistry.
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