About: A Monolithiated and Its Related 1,3-Dilithiated Allylsilane: Syntheses, CrystalStructures, and Reactivity

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2006/volume_128/issue_25/w
Subject	Communication
Title	A Monolithiated and Its Related 1,3-Dilithiated Allylsilane: Syntheses, CrystalStructures, and Reactivity
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2006/volume_128/issue_25/101021ja061286w/m/print http://hub.abes.fr/acs/periodical/jacsat/2006/volume_128/issue_25/101021ja061286w/m/web
related by	http://hub.abes.fr/acs/periodical/jacsat/2006/volume_128/issue_25/101021ja061286w/authorship/2 http://hub.abes.fr/acs/periodical/jacsat/2006/volume_128/issue_25/101021ja061286w/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2006/volume_128/issue_25/101021ja061286w/authorship/3
Author	Strohmann Carsten Dilsky Stefan Lehmen Klaus
Abstract	Treatment of Me2Si(CH2CHCH2)(CH2NC5H10) with 1 or 2 equiv of t-BuLi afforded the mono- or dilithiated allylsilanes, which crystallize as a tetramer and a hexamer from pentane. The product selectivity in trapping reactions is influenced by the ability of both the solvent and the electrophile to coordinate the lithium center.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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