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À propos de : Gold(I) Catalyzed Isomerization of 5-en-2-yn-1-yl Acetates: An EfficientAccess to Acetoxy Bicyclo[3.1.0]hexenes and 2-Cycloalken-1-ones        

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  • Gold(I) Catalyzed Isomerization of 5-en-2-yn-1-yl Acetates: An EfficientAccess to Acetoxy Bicyclo[3.1.0]hexenes and 2-Cycloalken-1-ones
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  • The gold(I) catalyzed rearrangement of 5-en-2-yn-1-yl acetates into functionalized acetoxy bicyclo[3.1.0]hexenes is described. The mild reaction conditions employed allow the efficient and rapid synthesis of a variety of such bicyclic compounds via a sequence of two gold(I)-catalyzed isomerization steps. Acetoxy bicyclo[3.1.0]hexenes products can be further transformed to 2-cycloalkenones by simple methanolysis.
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