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À propos de : C-H Bond Activation of Arenes by a Transient η2-Cyclopropene NiobiumComplex        

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  • C-H Bond Activation of Arenes by a Transient η2-Cyclopropene NiobiumComplex
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  • The intermolecular C−H bond activation of benzene occurs under very mild conditions (room temperature) via a rare stereospecific 1,3-H addition on an unsaturated η2-cyclopropene intermediate generated by a β-H abstraction of CH4 from TpMe2NbMe(c-C3H5)(MeC⋮CMe) to give TpMe2NbPh(c-C3H5)(MeC⋮CMe).
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