Documentation scienceplus.abes.fr version Bêta

À propos de : The Mechanism of Polymerization of Butadiene by “Ligand-Free” Nickel(II)Complexes        

AttributsValeurs
type
Is Part Of
Subject
Title
  • The Mechanism of Polymerization of Butadiene by “Ligand-Free” Nickel(II)Complexes
has manifestation of work
related by
Author
Abstract
  • The polymerization of 1,3-dienes has been well-studied using an array of metal-containing complexes. Although a variety of (π-allyl) Ni(II) catalysts have been shown to be active for diene polymerization, details concerning the mechanism of chain growth are largely speculative and supported primarily by DFT calculations. The observation by low-temperature NMR spectroscopy of the key intermediates and the catalyst resting states in the chain growth are described here and provide a more complete and detailed mechanism of butadiene polymerization.
article type
is part of this journal



Alternative Linked Data Documents: ODE     Content Formats:       RDF       ODATA       Microdata