About: Amine-Catalyzed Direct Aldol Addition

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2007/volume_129/issue_23/w
Subject	Communication
Title	Amine-Catalyzed Direct Aldol Addition
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2007/volume_129/issue_23/101021ja071926a/m/web http://hub.abes.fr/acs/periodical/jacsat/2007/volume_129/issue_23/101021ja071926a/m/print
related by	http://hub.abes.fr/acs/periodical/jacsat/2007/volume_129/issue_23/101021ja071926a/authorship/3 http://hub.abes.fr/acs/periodical/jacsat/2007/volume_129/issue_23/101021ja071926a/authorship/2 http://hub.abes.fr/acs/periodical/jacsat/2007/volume_129/issue_23/101021ja071926a/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2007/volume_129/issue_23/101021ja071926a/authorship/4
Author	Mahrwald Rainer Markert Morris Mulzer Michael Schetter Bernd
Abstract	An efficient organo-catalytic, highly syn-stereoselective method for aldol additions between enolizable aldehydes and hydroxyacetone as well as dihydroxyacetone is disclosed. Reactions proceed in the presence of tertiary amines at room temperature. The aldol adducts can be obtained in good to high yields and with high degrees of syn-diastereoselectivity. This new aldol reaction provides an operationally simple protocol for the stereocontrolled synthesis of carbohydrates
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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