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An Unconventional Approach to the Enantioselective Synthesis ofCaryophylloids
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http://hub.abes.fr/acs/periodical/jacsat/2008/volume_130/issue_10/w
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Title
An Unconventional Approach to the Enantioselective Synthesis ofCaryophylloids
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http://hub.abes.fr/acs/periodical/jacsat/2008/volume_130/issue_10/101021ja8003705/m/print
http://hub.abes.fr/acs/periodical/jacsat/2008/volume_130/issue_10/101021ja8003705/m/web
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http://hub.abes.fr/acs/periodical/jacsat/2008/volume_130/issue_10/101021ja8003705/authorship/1
http://hub.abes.fr/acs/periodical/jacsat/2008/volume_130/issue_10/101021ja8003705/authorship/2
Author
Corey E. J.
Larionov Oleg V.
Abstract
The chiral enones 4 and ent-4 have been synthesized enantiomerically as configurationally stable compounds that can be used for the synthesis of caryophylloids. For instance, ent-4 has been converted to the marine natural product coraxeniolide A.
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Journal of the American Chemical Society
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