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À propos de : Pt(II)- and Pt(IV)-Bridged Cofacial Diporphyrins via Carbon−Transition Metal σ-Bonds        

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  • Pt(II)- and Pt(IV)-Bridged Cofacial Diporphyrins via Carbon−Transition Metal σ-Bonds
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  • A directly Pt(IV)-bridged cofacial diporphyrin has been synthesized by the cyclometalation reaction of β-pyridylporphyrin with a Pt(IV) salt. Upon treatment with methylhydrazine, the Pt(IV) bridge is reduced to the Pt(II) center, resulting in a Pt(II)-bridged cofacial dimer with a helicity inversion of the complex as well as change in electronic communication through the metal bridge.
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