| Title
| - Adsorption of Benzenesulfonic Acid; 3,3‘,3‘ ‘-Phosphinidynetris-,Trisodium Salt; and Di(μ-tertiobutylthiolato) Dicarbonyl,Bis(benzenesulfonic acid, 3,3‘,3‘ ‘-phosphinidynetris-, Trisodium Salt)Dirhodium from Aqueous Solutions on Silica
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| Abstract
| - Adsorption studies of benzenesulfonic acid; 3,3‘,3‘ ‘-phosphinidynetris-, trisodium salt (TPPTS); and di(μ-tertiobutylthiolato) dicarbonyl, bis(benzenesulfonic acid, 3,3‘,3‘ ‘-phosphinidynetris-, trisodium salt)dirhodium ([Rh(μ-StBu)(CO)(TPPTS)]2) from aqueous solutions on four different silica samples were carriedout at 25 °C. The isotherms obtained were correlated by several models, among which Fowler's one wasfound to be the most satisfactory. The solubilities of TPPTS and [Rh(μ-StBu)(CO)(TPPTS)]2 in water atfour temperatures in the range (25−80) °C were also studied.
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