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À propos de : An Efficient Stereoselective Synthesis of Cytotoxic 8-Epipuupehedione        

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  • An Efficient Stereoselective Synthesis of Cytotoxic 8-Epipuupehedione
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  • An efficient and highly stereoselective synthesis of cytotoxic 8-epipuupehedione (1b) was achieved startingfrom natural (−)-drimenol (6). The key step to obtain stereoselectivity was the simultaneous demethylationand oxidation of the dihydrobenzopyran methoxy derivatives 10a and 10b.
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