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The effect of the base strength upon the structure of the transition state in E2 reactions. Kinetics of eliminations from 2-arylethyltrimethylammonium bromides promoted by sodium phenoxide and sodium m-nitrophenoxide in N,N-dimethylformamide
Total synthesis of (.+-.)-decamine. A convenient scheme for the synthesis of cis- and trans-quinolizidine alkaloids
Reactions of lithio derivatives of carboxylic acids. 1. 3-Methyl-2-butenoic acids
Highly strained ring systems. Hydrolysis of tricyclo[4.1.0.02,7]hept-3-yl derivatives. Evidence for participation of bicyclo[1.1.0]butane ring
Novel C19 trienes from abietic acid in fluorosulfonic acid
Podophyllotoxin derivatives. 3. The remaining diastereo C-4 alcohols and ketone of the L series
Photolysis and thermolysis of some 2-azido-2'-arylazobiphenyls
Synthesis of ι-methoxy-1,2-dihydronaphthalenes. Gas phase pyrolysis of 1-(2'-, 3'-, and 4'-methoxyphenyl)-3,-butadienes
The role of the generalized anomeric effect in the conformational analysis of 1,3-dioxacycloalkanes. Conformational analysis of 3,5-dioxabicyclo[5.1.0]octanes and 3,5,8-trioxabicyclo[5.1.0]octanes
A novel reaction of some fluorospiro[isobenzofuran-1(3H),4'-piperidin]-3-ols in 97% formic acid
Stereoisomerism of cyproheptadine N-oxide
Reactions of phosphorus compounds. 37. Preparation of .beta.-iminopropyl- and .beta.-aminopropenyltriphenylphosphonium bromides and the use of the latter in heterocyclic synthesis
Generation of the trans enolate of chloroacetaldehyde via a .beta.-oxido carbenoid
Prostaglandins and congeners. 11. Synthesis of dl-13-hydroxyprostanoic acids
The facile, regiospecific protonation of alkenes. A model system
.beta.,.gamma.-Unsaturated diazo ketones. A new initiator for polyolefinic cationic cyclization
Dehydroaporphines. Dichlorocarbene addition to dehydronuciferine
Influence of a 9.alpha.-fluorine on the epoxidation of an 11.beta.-hydroxy-.delta.4-3-keto steroid with basic hydrogen peroxide
An improved preparation of phenolic [1.1.1.1]metacyclophanes
Reversals in regiospecificity. The reactivity of vinylogous amides toward bis-electrophiles
Carbon acids. 13. Acidifying effects of phenylthio substituents
A convenient synthesis of diaryl methylphosphonates and transesterification products therefrom
Pheromone synthesis. 4. A synthesis of (.+-.)-methyl n-tetradeca-trans-2,4,5-trienoate, an allenic ester produced by the male dried bean beetle Acanthoscelides obtectus (Say)
Catalyses of Polymer Complexes. 4. Polysoap-Catalyzed Decarboxylation of 6-Nirtobenzisoxazole-3-carboxylate Anion. Importance of the Hydrophobic Environment in Activation of the Anion
Reduction of organic halides with zinc-copper to deuterated compounds and a convenient carbon-13 magnetic resonance method of deuterium analysis
Synthesis of 1-.alpha.-cumyl-1,2,3,6-tetrahydropyridazine-3,6-dione
Secalonic acids D and F are toxic metabolites of Aspergillus aculeatus
o-Chloranil-azlactone adducts and their conversions to unsaturated amino acid derivatives
The molecular structure of Athabasca asphaltene. Cleavage of the carbon-sulfur bonds by radical ion electron transfer reactions
Masthead
A convenient determination of .sigma.+ values
Stereospecific synthesis of (2S,3R)-2-amino-3-mercaptobutyric acid - an intermediate for incorporation into .beta.-methyllanthionine-containing peptides
Nuclear magnetic resonance determination of enantiomeric composition and absolute configuration of .gamma.-lactones using chiral 2,2,2-trifluoro-1-(9-anthryl)ethanol
Autocatalysis in the nitrosation of dihexylamine
Stereochemistry of organophosphorus cyclic compounds. 6. Stereochemistry of the reaction between sulfenyl chlorides and trivalent phosphorus compounds
A ring expansion route to benzo substituted medium- and large-ring systems. Synthesis of trans-7,8-benzocyclododeca-5,7-dien-1-one
Metal hydride reduction of bicyclo[2.2.2]octa-2-ones. Preparation and stereochemistry of 5-substituted bicyclo[2.2.2]octan-2-ols
Specific directing effects in the opening of vicinal hydroxy epoxides
A new method for protecting amines
The chemistry of carbanions. 30. Stereochemistry of the metal-ammonia reduction of 7-tert-butyl-10-methyl-.DELTA.1,9-octal-2-one
1-Cycloheptatrienylidene-4-cyclopentadienylidene-2,5-cyclohexadiene system
Ferric chloride in ether. A convenient reagent for the conversion of epoxides into chlorohydrins
Selective halogen-lithium exchange in 2,5-dibromobenzenes and 2,5-dibromopyridine
Concerning the significance of product development control as an important factor in the reduction and alkylation of model ketone systems
Synthesis of 5-(tert-alkyl)resorcinols
Gnididione, a new furanosesquiterpene from Gnidia latifolia
The association constants of organic complexes of iodine. A competitive equilibrium study
Synthetic approaches to the quinolinequinone system of streptonigrin
A simple, empirical function describing the reaction profile, and some applications
Determination of ionization constants of alkaloids by paper electrophoresis
Structure of Satratoxin H, a metabolite of Stachybotrys atra. Application of proton and carbon-13 nuclear magnetic resonance
Carbon acids. 12. Acidifying effects of phenyl substituents
Thallium in organic synthesis. 45. Synthesis of aromatic fluorides
Methylthioformaldine. A new formaldehyde anion equivalent
Fluorine-19 nuclear magnetic resonance. Electric field shifts of bicyclic fluorides
Preparation and properties of small ring bis-annelated benzenes
A reinvestigation of the reaction of .alpha.-pinene with hypochlorous acid
Thermal and base-catalyzed isomerizations of birdcage and half-cage compounds
Organic reactions at high pressure. Cycloadditions with enol and dienol derivatives
Synthesis of antibacterial p-quinols from marine sponges. Synthetic applications of "masked" quinones
Oxidation of 1,3-dihydrobenzo[c]selenaphene (2-selenaindan) to 2,2'-diformyldibenzyldiselenide
Studies in .beta.-lactams. 5. Enolate amination with O-mesitylenesulfonylhydroxylamine
Four new mycotoxins of Aspergillus clavatus related to tryptoquivaline
Pinol derivatives from lithium aluminum hydride reduction of cineole chlorohydrin
Syntheses of the optically active multilayered [2.2]paracyclophanes with known absolute configurations
Homogeneous catalytic cyclization and oxidation of diols
Asymmetric induction. Enantioselective alkylation of cyclohexanone
Transformation of benzoin to tetraphenylfuran in the presence of p-toluenesulfonic acid in boiling xylene
Synthesis of secondary and tertiary carbinamines from N-alkylidenearenesulfenamides and alkyl- and aryllithium reagents
Preparation of 6-(bromomethyl)-2,4-pteridinediamine hydrobromide and its use in improved syntheses of methotrexate and related compounds
Rates of thiol-disulfide interchange reactions between mono- and dithiols and Ellman's reagent
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