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Carbon-13-labeled benzo[a]pyrene and derivatives. 1. Efficient pathways to labeling the 4, 5, 11, and 12 positions
Efficient intramolecular monophenol oxidative coupling
Alkyl nitrite-metal halide deamination reactions. 5. In situ generation of nitrosyl halides. Effective product control from nitrosyl chloride diazotization of primary aliphatic amines in N,N-dimethylformamide
1,4-Diketones from skipped acetylenes
Azoloquinoxaline N-oxides
Novel applications of the potassium chlorate-osmium tetroxide oxidizing system. Synthesis of .alpha.-dicarbonyl derivatives from acetylenic compounds. Synthesis of a 2,3-dihydroxy-1,4-dione from a 2,5-dialkylfuran
Protoadamantyl-adamantyl rearrangement. Methyl-d3 isotope effects and product compositions in the solvolysis of 4-endo- and 4-exo-4-methylprotoadamantyl and 1-methyl-2-adamantyl derivatives. Evidence for bridging
Three isomeric 1,3-dimethyl-5-(dihydropyran-2-yl)-2,4-pyrimidinediones. Palladium-catalyzed synthesis and spectrometric properties
Preparation of .alpha.-halo sulfoximines
Stereocontrolled preparation of chiral (E)-1-alkenyl sulfoxides. Efficient reduction of alkenyl sulfoxides to the corresponding alkenyl sulfides
Alkenes from base-promoted eliminations of .alpha.-halo sulfoximines
Synthesis and reactions of some N-acylated and N-sulfonylated N,N'-dialkylureas
Nitroxides derived from 3,4-dihydro-2,5-dimethyl-2H-pyrrole 1-oxide: a new series of minimum steric perturbation lipid spin labels
Temperature-dependent rearrangement of 2-(2-furyl)-2-lithio-1,3-dithiane
An efficient conversion of ketones to .alpha.,.beta.-unsaturated ketones
Photochemical transformations of chalcone oxides
Mechanism and catalysis for o-hydroxyacetophenone phenylhydrazone formation
Base-catalyzed reactions of .alpha.,.beta.-unsaturated esters and nitriles. 3. Alkali metal catalyzed di- and trimerization of acrylates
1,2-Diphenyl-3-azanaphtho[b]cyclobutadiene
Chemistry of .alpha.,.beta.-unsaturated thione dimers. 1. Preparation of .alpha.,.beta.-unsaturated thione dimers and thermolysis of these dimers in the presence of acrylonitrile or acrylamide
Total synthesis of anthracyclinones via intramolecular base-catalyzed cyclizations
Condensation reactions of carbanions and ylides derived from .alpha.-halo sulfoximines
Vinyl phenyl selenide: a +CH:CH- synthon
Secondary orbital interactions determining regioselectivity in the Diels-Alder reaction. 4. Experimental and theoretical examination of the reaction of acrylonitrile with 1-(phenylthio)-2-methoxy-1,3-butadiene. Determination of the conformations of the four cyclohexene adducts by proton NMR
Base-catalyzed alkylation of cyclopentadiene rings with alcohols and amines
Studies on total synthesis of the olivomycins
Deamination of cytidine by bisulfite: mechanism at neutral pH
Reactions of phosphorus compounds. 39. Synthesis and reactions of [2-(aziridin-1-yl)alkenyl]triphenylphosphonium bromides
Scope of the homo-Diels-Alder reaction
Rearrangement reaction of 1-chloro-4-[p-(carbomethoxy)thiophenoxy]-2-butanone with potassium phthalimide
Synthesis of 3-carboethoxyoxindoles
Tri-tert-butylmethylsilane
.alpha.,.alpha.-Dichlorocyclopropanols. Attenuation of cyclopropyl rearrangement processes in the 3-bicyclo[4.1.0]heptene system. A novel regiospecific 2-chlorotropone synthesis
Template synthesis of macromolecules. Selective functionalization of an organic polymer
Chemical evolution. 31. Mechanism of the condensation of cyanide to hydrogen cyanide oligomers
Proximity effects. Part 4. Alkaline hydrolysis of methyl carboxylates, alkyl acetates, and alkyl carboxylates. Steric effects in carboxylic acid derivatives and related systems
Roles of heteroatoms in solvolytic reactions. 4. Solvolysis of the exo and endo esters of 2-thiabicyclo[2.2.1]heptan-6-ols
Kinetics of the thermolysis of 3,3-bis(p-anisyl)-1,2-dioxetane
The 1-hetero-3-cyclohexanone system. Carbon-13 magnetic resonance, transannular effects, and conformational analysis
Ochtodene and ochtodiol: novel polyhalogenated cyclic monoterpenes from the red seaweed Ochtodes secundiramea
New synthesis of (.+-.)-emetine from tetrahydroprotoberberine precursors via an .alpha.-diketone monothioketal intermediate
Rearrangement approaches to polycyclic skeletons. 1. Bridgehead-substituted bicyclo[3.2.1]octene derivatives from bicyclo[2.2.2]octene precursors
Stereospecific cyclizations of iminium salts from .alpha.-amino acid decarbonylation. Synthesis of 8- and 13-methylberbines
Solvolysis of virescenol B 19-tosylate
Reactions of heteroaromatic cations with nucleophilic reagents. Addition of methoxide ion to 2,6-diphenyl- and 4-methoxy-2,6-diphenylpyrylium cations
Liquid-phase syntheses of protected peptides on the new 3-nitro-4-(bromomethyl)benzoylpoly(ethylene glycol) support
Masthead
Mechanism of aryl group migration in the formation of stilbenes from 1,1-bis(p-hydroxyaryl)ethane 2-O-aryl ethers
Stereoselective alkylation of cyclic ketones by dialkylamino- and aryloxy(methyl)magnesium compounds
Pteridines. 45. Synthesis and properties of some isothiazolo[4,5-b]pyrazines and isothiazolo[4.5-g]pteridines
Fluorinated pyrimidine nucleosides. 2. Reaction of 2,2'-anhydro-1-.beta.-D-arabinofuranosyl-5-fluorocytosine hydrochloride with nitrogen and sulfur nucleophiles
Photochemistry of 2-acetyl-3-phenylnorbornanes: influence of a .beta.-phenyl group on carbonyl reactivity in relation to the geometry of both chromophores
Annelation of ethyl propiolate with ethyl pipecolate
Solvolysis of 2-oxiryl-2-propyl p-nitrobenzoate. Evidence on the mode of stabilization of the oxirylcarbinyl cation
Catalysis in aromatic nucleophilic substitution. 3. Reactions of piperidine with 2-methoxy-3-nitrothiophene and 2-methoxy-5-nitrothiophene in methanol
C-12 substituted prostaglandins: synthesis and biological evaluation of (.+-.)-12-hydroxyprostaglandin F2.alpha. methyl ester
Steric effects. 13. Composition of the steric parameter as a function of alkyl branching
Reactions of cyclometalated palladium complexes with organolithium compounds or Grignard reagents. Selective Ortho alkylation and arylation of benzaldehydes, azobenzenes, and tertiary benzylic amines
Marine natural products: sesquiterpene alcohols and ethers from the sea hare aplysia dactylomela
Aleuritic acid, an abundant source of prostanoid synthons
Lithiation of ethyl 2,4,6-triisopropylbenzoate adjacent to oxygen: the .alpha.-lithioalkyl alcohol synthon
Heterocyclic studies. 46. Reaction pathways of the 2-acyl-1,2-diazabicyclo[3.2.0]-hept-3-en-6-one system
Studies on decarboxylation reactions. 3. Micellar catalysis in the decarboxylation of 5-amino-1,3,4-thiadiazole-2-carboxylic acid
Cyclic peroxides by intramolecular peroxymercuration of unsaturated hydroperoxides
Antineoplastic agents. 58. Synthesis of 3-aryl-5-bromo-2(5H)-furanones
Association phenomena. 5. Synthesis and properties of 1,4-dipolar substituted cyclohexenes
Rapid removal of protecting groups from peptides by catalytic transfer hydrogenation with 1,4-cyclohexadiene
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