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Reaction of copper enolates of esters with propargylic systems. Facile preparation of 3,4-dienoic esters, stereoselective rearrangement to (2E,4Z)- and (2E,4E)-dienoic esters, and stereoselective synthesis of a fragrance from the Bartlett pear
Intramolecular phenoxymercuration of 2-allylphenols. Regioselectivity and stereochemistry
Synthesis of 4-amino-3-hydroxy-6-methylheptanoic acid by a modified Reformatsky reaction
Position of nucleophilic attack on propargylic .tautm. allenylic cations. An ab initio molecular orbital calculation
Masthead
Stepwise synthesis of N-acetylneuraminic acid and N-acetyl[1-13C]neuraminic acid
Methoxyphosphonium ions; intermediates in the Arbuzov reaction
Neighboring group participation in the conversion of .beta.-substituted ethanesulfonate salts to .beta.-substituted ethanesulfonyl chlorides
Ozonation of nucleophiles. 7. Dibenzyl sulfides
.alpha. Addition and ortho metalation of phenyl isocyanide
Studies on Friedel-Crafts chemistry. 3. A new preparative method of 2-tert-butyl-p-xylene by the aluminum chloride-nitromethane catalyzed tert-butylation of p-xylene with 2-tert-butyl- and 2,6-di-tert-butyl-p-cresol
.pi.-Complexed .beta.-arylalkyl derivatives. 5. Polar effects in the formolysis of .pi.-complexed 9-benzonorbornenyl and 9-benzonorbornadienyl methanesulfonates
Relative reactivity of substituted 2-alkoxy- and 2-phenoxy-3,4-dihydro-2H-pyrans with tert-butyl hypochlorite. Effect of substituents on reactivity and products
Organofunctional alkylstannanes via Michael-type additions
Reductive alkylation of phenazine. Electrochemical preparation of 5,10-dihydro-5,10-dimethyl and 5,10-dihydro-5,10-diethyl derivatives
Tumor inhibitors. 126. New cytotoxic neolignans from Aniba megaphylla Mez
Sensitized photolyses of methanesulfonyl azide in hydrocarbons
Chemistry of N-halo compounds. 27. Rearrangement of N-chloro-N-acetyl-1-aminoadamantane by aluminum chloride
Carbon-13 nuclear magnetic resonance study of iodine-sulfide charge-transfer complexes
Direct .alpha.-lithiation of phenoxyacetic acid and electrophilic substitution
Styrene bromination: evidence for a bridged rate-determining transition state
Solid-state racemization of 4,4'-diamino-1,1'-binaphthyl
Reactions of 1,1-disubstituted olefins containing electron-attracting substituents with methylphenyldiazomethanes
The .alpha. effect in .alpha.-chlorofluoro ketones
Migration of acyl groups in acetyl-alkoxycarbonyl mixed diacyl derivatives of o-aminophenol
Introduction of a new 1,3-electrophilic carbon-nitrogen-carbon annulation reagent in the synthesis of 2,2'-anhydrodihydro-5-azathymidine
Purine N-oxides. 65. The mechanisms of the reactions of 3-acetoxyxanthine
Photochemistry of phenyl alkyl ketones in the presence of organophosphorus(V) compounds
Synthesis of 4,5-dicyano-2-methylthio-1,3-dithiolylium salts: a supposedly impossible alkylation
Total synthesis of (.+-.)-sarracenin
Synthesis and epoxidation kinetics of some fused-ring cyclopropenes
Imidazo[1,2-a]pyridine 1-oxide. Synthesis and chemistry of a novel type of N-oxide
Facile ring cleavage of prostaglandin epoxy ketones
Mass spectrometry of pyrimidine anhydronucleosides
Synthesis of epoxides with electronegative substituents. Photometric substrates for epoxide hydrase
Enhanced nucleophilic reactivity (.alpha. effect) in the reaction of peroxobenzoate anions with p-nitrophenyl acetate
Alkaloids of Thalictrum. 25. Six new bisbenzylisoquinoline alkaloids from Thalictrum rugosum
Hydroformylation catalyzed by cis-chelated rhodium complexes. Extension to polymer-anchored cis-chelated rhodium catalysts
Isoquinolines. 7. Reaction of ethylene oxide with isoquinolines. Novel isoquinolone and oxazolidine formation
Chemistry of carbanions. 31. Cyclization of the metal enolates from .omega.-bromo ketones
Ring-opening reactions of .alpha.-oxy epoxides with tert-butyl dilithioacetoacetate
Syntheses and chiroptical properties of (-)-ditwist-brendane and (+)-D3-trishomocubane
Acid-catalyzed isomerization of 2-protoadamantenone to 8,9-dehydro-2-adamantanone
Synthesis of enol chloroformates
Protecting groups. 7. A novel type of neighboring group participation involving pyridine N-oxides in acylation and phosphorylation. 1
Fluorination with xenon difluoride. Stereochemistry of fluorine addition to phenyl-substituted cycloalkenes
An efficient synthesis of .gamma.-methylene-.gamma.-butyrolactone (.alpha.'-angelicalactone). Application to the synthesis of deoxyobtusilactone and deoxyisoobtusilactone
Phenylseleno neighboring group. Solvolysis of 2-phenylselenoethyl chloride
Synthesis of trans-15-n-butyl-16-methyldihydropyrene. Synthetic access to 1,2,3-trisubstituted benzene derivatives via direct alkylation of 1,3-bis(4',4'-dimethyl-2'-oxazolinyl)benzene
Pteridines. 44. A convenient synthesis of 6-formylpterin
Metal-ammonia reduction of cis-8,10-dimethyl-1(9)-octal-2-one
Synthesis via silyl alkenyl ethers. 14. Dimethyldicyanosilane: a reagent for concurrent silylation and cyanosilylation of .beta.-diketones
Reaction of santonin with hydroxylamine
Carbon acidity. 55. Acidity of 8,8-dimethyl-8,12b-dihydrobenzo[a]fluoranthene. Conjugating effect of a coplanar phenyl
Polyamines from cyanobutadienes
Reactions of 2-methyl-2H-cyclopenta[d]pyridazine with benzenediazonium tetrafluoroborate and N-nitrosoacetanilide
Reaction of cis- and trans-4-tert-butyl-1-methoxy-1-phenylphosphorinanium hexafluorophosphate with aqueous hydroxide. Axial vs. equatorial displacement of methoxide
An efficient method for the preparation of furanoid and pyranoid glycals
Thermal isomerization of allylic alcohols to saturated ketones
Pteridines. 43. A facile synthesis of 6-chloropterin and 2,4-diamino-6-chloropteridine
Silane reductions in acidic media. 10. Ionic hydrogenation of cycloalkenes. Stereoselectivity and mechanism
Thermal rearrangement of halocineole to halopinol derivatives
Protecting groups. 6. Interaction of 2-picoline 1-oxides with acylating and phosphorylating agents. A case of product distribution control
Pyrolysis of N-p-toluenesulfonylsulfilimines
Studies on vitamin D (calciferol) and its analogs. 13. 3-Deoxy-3.alpha.-methyl-1.alpha.-hydroxyvitamin D3, 3-deoxy-3.alpha.-methyl-1.alpha.,25-dihydroxyvitamin D3, and 1.alpha.-hydroxy-3-epivitamin D3. Analogs with conformationally biased a rings
Syntheses of diaza-, azaoxa-, diazaoxa-, and triazasulfonium ions
A convenient method for the stereoselective reduction of alkynes to alkenes by the new reagents magnesium hydride-copper(I) iodide and magnesium hydride-copper(I) tert-butoxide
The spiropentyl to 3-methylenecyclobutyl cation rearrangement avoids CH+-trimethylenemethane or the 1-bicyclo[1.1.1]pentyl cation
Chemistry of benzyl hydroperoxide
Heterocyclic studies. 45. Thermal isomerization of a 1,2-diazepine to a 1,3-diazepine
Thermolysis and photolysis of unsaturated ketones. 26. Preparation of bicyclo[2.2.2]octan-2-ones and bicyclo[2.2.1]heptan-2-ones by thermal cyclization of unsaturated ketones. A facile synthesis of (+)-camphor from (+)-dihydrocarvone
Dipolar micelles. 6. Catalytic effects of betaine-like micelles on the hydrolysis of substituted phenyl esters
Preparation and crystal structure of 6-acetyl-1-iodocodeine
A stereoselective Wittig reagent and its application to the synthesis of 25-hydroxylated vitamin D metabolites
Syntheses of electronegative substituted tetrathiafulvalene derivatives
Isocyanide-metal exchange. The synthesis of masked acylcyanides
Novel photochemically induced carbon monoxide insertion of an enone-iron tetracarbonyl complex to yield a lactone
Isonucleosides. 2. Purine and pyrimidine derivatives of 1,4-anhydro-2-deoxy-D-arabinitol
Mercury in organic chemistry. 13. Stereospecific synthesis of .alpha.,.beta.-unsaturated ketones via acylation of vinylmercurials
Addition reaction of benzene to .alpha.-substituted chalcone derivatives by means of palladium(II) acetate
Atomic oxygen. 8. Reactions of methylenecycloalkanes with oxygen (3P) atoms
Imine prototropy: synthetic consequences in the generation of metalloenamines
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