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2,6-Diboraadamantane, a novel structure with unusual characteristics, via cyclic dihydroboration of 1,3,5,7-cyclooctatetraene
Masthead
Reduction of azanaphthalenes by sodium borohydride in trifluoroacetic acid
Organoselenium-induced ring closures: cyclization of dienes with "PhSeOH" to form cyclic ethers
Reaction of alkyl halides and alkyl methyl ethers with nitronium tetrafluoroborate in acetonitrile
Use of nitrogen-15-proton and nitrogen-15-carbon-13 coupling constants for the measurement of uracil monoanion tautomerism
Hard acid and soft nucleophile system. New efficient method for removal of benzyl protecting group
New syntheses of tetrathiafulvalene
Stereocontrolled cis addition of organocopper reagents RCu.cntdot.BR'3 to .alpha.,.beta.-acetylenic carbonyl compounds
Jesromotetrol carbon-13 nuclear magnetic resonance. Boric and phenylboronic acids as assignment aids for 1,2- and 1,3-diols
Fluoroalkanesulfonyl chlorides
Synthesis of new branched-chain cyclitols having epi and allo configuration and myo configuration respectively from 3-O-benzyl-5,6-dideoxy-5-[C-(1,3-dithian-2-yl)]-6-nitro-D-allofuranose and -L-talofuranose
Reaction of unsaturated compounds with hypofluorous acid
Synthesis of 5-(methylthio)-, 5-(methanesulfinyl)-, and 5-(methanesulfonyl)uracil and reaction of the methyl hypobromite adduct of 5-bromouracil with carbonylmethylene compounds
Side reactions in peptide synthesis. 11. Possible removal of the 9-fluorenylmethyloxycarbonyl group by the amino components during coupling
Acid-catalyzed dehydration and acetolysis of tertiary methyl- and tert-butylcarbinols. Empirical force field treatment of tert-butyl/methyl reactivity ratios in solvolysis reactions of alcohols and p-nitrobenzoates
Synthesis, stereochemistry, and rearrangement of 9-alkylthioxanthene-N-(p-toluenesulfonyl)sulfilimines
Highly stereoselective synthesis of (.+-.)-.alpha.-multistriatin
Heterocyclic Meisenheimer complexes: kinetic and equilibrium data for methoxide ion attack on various disubstituted 2,4-Y,Z-thiophenes and -selenophenes in methanol
Basicity measurements in aqueous-organic solvents. 1. The 20% ethanol-aqueous sulfuric acid system
Facile synthesis of 4-acetoxy-2-methyl-2-butenal, a vitamin A precursor, from isoprene chlorohydrin
Bimolecular reductions of aromatic ketones and aldehydes with the n-butyllithium-Fe4S4(SPh)4 system
General acid-catalyzed decomposition of alkyl xanthates
Syntheses of amino acids and related compounds. 22. Efficient synthesis of 3-substituted aspartic acids
Charge delocalization, solvation, and stability of oxycarbenium ions
1,2-Bis(diphenylphosphino)-1-phenylethane: a chiral ditertiary phosphine derived from mandelic acid used as a ligand in asymmetric homogeneous hydrogenation catalysts
Ortho ester hydrolysis: concerted nature of the dialkoxycarbonium ion forming stage
New method for direct conversion of amides to amines
Free-radical cyanation. Novel free-radical reaction of methyl cyanoformate or cyanogen with 2,4-dimethylpentane
Elimination reactions. 3. Light-assisted hydrocyanic acid elimination from 2-[p-(N,N-dimethylamino)phenyl]-2,3,3-tricyanopropionamide
Study of the A-ring conformation in 4,4-dimethyl-3-keto steroids
Photochemistry of bicyclic compounds. The di-.pi.-methane rearrangement of 5-methylene-2-norbornenes
Pteridines from .alpha.-phenyl-N,N-dimethylacetamidine
Mild, selective, general method of ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium
Photoinduced reactions. 39. Photochemistry of the imide system. 9. Norrish type I reaction of aliphatic cyclic imides. General reaction pattern, competition with type II processes, and some synthetic application
Cyano transfer from acetonitrile to aromatic compounds
Optically active amines. 26. Spectral observations on chiral Schiff bases
Cyclic peroxides. 80. 1,4-Dimethyl-2,3,7-trioxabicyclo[2.2.1]hept-5-ene: synthesis and characterization
Synthesis of an 11-deoxy-8-azaprostaglandin E1 intermediate
Recent Reviews
Configurational and conformational stereoselectivity in the acid-catalyzed ring opening of 1-phenylcyclohexene oxides
Asymmetric reduction of ketones with sodium borohydride in the presence of hydroxymonosaccharide derivatives
Use of thionyl chloride for sulfurization of active methylene compounds. Dechlorination of .alpha.-chlorosulfenyl chlorides
Steroidal ethers. Analogs of 7-ketocholesterol
Structure and chemistry of the aldehyde ammonias. 3. Formaldehyde-ammonia reaction. 1,3,5-Hexahydrotriazine
Steroid photochemistry. Facile [4 + 2] adduct formation in the photocycloaddition of an enedione to olefins and dienes
Heterocycles. 182. Neighboring group interaction in ortho-substituted heterocycles. 2. 1,2,4-Oxadiazolylpyridines and pyrido[2,3-d]pyrimidine 3-oxides
1,3-Disubstituted phenalenes. 4. Preparation and properties of 1,9-dihetero-substituted phenalenyl cations
Thermolysis of diazodicyanoimidazole: products and rates, the effect of 18-crown-6
Synthesis of imidazo[1,5-a]-1,3,5-triazinones by cyclization-rearrangement
Mechanistic studies in photochemistry. 21. Photoextrusion of sulfur dioxide: general route to [2.2]cyclophanes
Reaction of enol silyl ethers with silver acetate-iodine. Synthesis of .alpha.-iodo carbonyl compounds
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