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Selective synthesis of complex aromatic alkenes. (1,4-Cyclohexadienyl)alkenes by tandem arylation-multistep reduction of .alpha.,.beta.,.gamma.,.delta.-unsaturated ketones
Convenient synthesis of alkyl amines via the reaction of organoboranes with ammonium hydroxide
Chair-boat conformer in 2,4,6,8-tetraphenyl-3-aza-7-thiabicyclo[3.3.1]nonan-9-one. X-ray diffraction analysis of a single crystal of the compound
Methoxymethyl cations. 2. Reactions with allylic ethers and sulfides in the gas phase
Measurement and estimation of the heats of vaporization of hydrocarbons
Photoelectron spectra of alkyl aryl selenides. Electronic and steric factors in the observation of rotamers
Tetrabutylammonium hydroxide: a reagent for the base-catalyzed dehydration of vicinal dihydrodiols of aromatic hydrocarbons. Implications to ion-pair chromatography
Acid-catalyzed rearrangement of [5.n.2]propella-.epsilon.-lactones
Photochemical and thermal reactions of aromatic Schiff bases
Synthesis of 5,5-dichloro-4-pentenoic acid by the Wittig reaction with bromotrichloromethane and triphenylphosphine
Direct amidation of aromatic compounds
Reactions of ketene acetals. 13. Synthesis of contiguously trihydroxylated naphtho- and anthraquinones
Mechanisms of elimination reactions. 35. Deuterium kinetic isotope effects and tunneling in the reaction of [2-[p-(trifluoromethyl)phenyl]ethyl]trimethylammonium ion with hydroxide ion in mixtures of water and dimethyl sulfoxide
Selective reductive carbonyl couplings with titanium
Preparation of highly reactive metal powders. New procedure for the preparation of highly reactive zinc and magnesium metal powders
Mechanisms of elimination reactions. 34. Deuterium and nitrogen isotope effects and Hammett correlations in the reaction of (2-arylethyl)trimethylammonium ions with hydroxide ion in mixtures of water and dimethyl sulfoxide
Synthesis of 2'-deoxynucleosides by deoxygenation of ribonucleosides
Dipole-stabilized carbanions: secondary (.alpha.-lithioalkyl)alkylamine synthetic equivalents from N,N-dialkyl-2,2-diethylbutyramides
Novel synthesis of .alpha.-substituted acrylic acids
Extension of the Nenitzescu reaction to a cyclic enamino ketone. One-step synthesis of 6-hydroxy-9H-pyrimido[4,5-b]indole-2,4-dione
Thiosulfonium ions by gas-phase methylation and thiomethylation of sulfur nucleophiles. 1. Methoxymethyl cations
Mechanism of the backbone rearrangement of amino steroids. High-field proton, deuterium, carbon-13, and hydrogen-1 two-dimensional nuclear magnetic resonance spectroscopic study of isoholamine and polydeuterated isoholamine
Total synthesis of methoxatin, the coenzyme of methanol dehydrogenase and glucose dehydrogenase
Regioselective Diels-Alder reaction of 2-substituted acrylonitriles with cyclic dienones and hydrolytic ring cleavage of the adducts
Synthesis and stereochemistry of thiaspiro-.alpha.-methylene-.gamma.-butyrolactones. Single-crystal x-ray diffraction analysis of 2,2,6,6-tetramethyl-9-methylene-7-oxa-1-thiaspiro[4.5]decan-8-one
Synthetic applications of 2-phenylselenenylenones. 2. Synthesis of dihydrojasmone and cis-jasmone
Synthesis of 1,6-diazaphenalene
Influence of the localization of the excitation energy on the photochemistry of .alpha.,.beta.-epoxy ketones
Oxyfunctionalization of hydrocarbons. 11. Hydroxylation of benzene and alkylbenzenes with hydrogen peroxide in hydrogen fluoride/boron trifluoride
Cycloaddition of substituted bicyclo[3.2.1]octa-2,6-diene with 4-phenyl-1,2,4-triazoline-3,5-dione
Photoreactivity of 2- and 3-substituted benzo[b]thiophene 1-oxides in solution
Some guaiol oxidation products
Sulfinic acids and related compounds. 13. Unsymmetrical disulfides based on methyl 4-mercaptobutanesulfinate and 4(S)- or 4(R)-mercaptoprolines
Total synthesis of (.+-.)-multifidene, the gamete attractant of the phaeophyte Cutleria multifida
Reaction of di-tert-butylnitroxide with methyl trifluoromethanesulfonate. Unexpected formation of N-tert-butylhydroxylamine radical cation in trifluoromethanesulfonic acid
Nature of electrophiles and electron acceptors. Comparison of their molecular complexes with aromatic donors
Enedione-functionalized macrocycles via oxidative ring opening of furans
Substituent effects. 8. Basic strength of azatriptycene, triphenylamine, and some related amines
Nature of substituent effects in nuclear magnetic resonance spectroscopy. 2. Factor analysis of carbon-13 chemical shifts in unsaturated and aromatic halides
Structures of zeylenol and zeylena, constituents of Uvaria zeylanica (Annonaceae)
Aminoglycoside antibiotics. 4. Regiospecific partial synthesis of ribostamycin and 4"-thioribostamycin
Stereoselective alkylation and aldol reactions of (S)-(-)-.beta.-hydroxy-.gamma.-butyrolactone dianion
Steroids and related natural products. 98. Conversion of cyclohexanone to spiro[3,4-cyclohexano-4-hydroxybicyclo[3.3.1]nonan-9-one-2,1'-cyclohexane]
Mannich reaction product of dihydrocodeinone
Direct conversion of alcohols to alkanes
Functionalization of alkenes and alkynes with [hydroxy(tosyloxy)iodo]benzene. Bis(tosyloxy)alkanes, vinylaryliodonium tosylates, and alkynylaryliodonium tosylates
Cesium carboxylates in dimethyl formamide. Reagents for introduction of hydroxyl groups by nucleophilic substitution and for inversion of configuration of secondary alcohols
Generation of 2,3-benzobicyclo[2.2.1]hept-2-ene-5,7-diyl diradicals via denitrogenation of appropriate azoalkanes and their mechanistic implications in the di-.pi.-methane rearrangement of benzonorbornadienes
Chemoselective reactions of 3-chloroisonicotinonitrile
Organotellurium chemistry. 4. Synthesis and reactions of tellurophthalide. The first alkyltellurenyl halides
Intrinsic linear interrelationships among physical and spectroscopic properties of halogen-containing molecules
Exceptionally rapid thermal isomerization of B-(3-hexyl)bis(2,5-dimethylcyclohexyl)borane. A sterically enhanced, highly efficient synthetic route for the conversion of internal acyclic olefins into terminal olefins and their derivatives
Chemistry of N-halo compounds. 33. Pyrolytic eliminations from N,N-dichloro derivatives of primary, secondary, and tertiary alkyl primary amines
Covalent hydration in 4-pyrimidinones. Detection through kinetics of bromination in aqueous acidic solution
Kinetics and mechanism of the reaction of 5-nitroisoquinolinium cations with 1,4-dihydronicotinamides
Regioselective total synthesis of furoventalene, a marine natural benzofuran, via the .beta.-vinylbutenolide annulation
Decaryiol, a new cembrane diterpene from the marine soft coral Sarcophyton decaryi
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