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Synthesis of .beta.-D-mannopyranosides and .beta.-L-rhamnopyranosides by glycosidation at C-1
Microbial stereodifferentiating reduction of 1,6-spiro[4.4]nonanedione, a gyrochiral diketone with two homotopic carbonyl groups
Rates of formation of some phenazines by cyclization of di- and monoimines of N-(2-aminophenyl)-p-benzoquinone
N-Phenylselenophthalimide. A useful reagent for the facile transformation of (1) carboxylic acids into either selenol esters or amides and (2) alcohols into alkyl phenyl selenides
Antitumor plants. 11. Diterpenoid and flavonoid constituents of Bromelia pinguin L
Restricted rotation in hydroxyphenyl ketones and fomaldehydes
Cycloaddition reactions of an o-quinoid 10-.pi.-electron system, 2H-pyrrolo[3,4-c]pyridine
Thermal decarboxylation of 3,17-dioxo-4.beta.,5-epoxy-5.beta.-androstan-19-oic acid and some transformations of the derived product
Formal total synthesis of (.+-.)-isocomene
Antitumor agents. 43. Conversion of bruceoside-A into bruceantin
Carbon-phosphorus heterocycles. Conformational analysis of substituted 1-phenyl-4-phosphorinanones and derivatives. Single-crystal x-ray diffraction analysis of 1-r,cis-2a,trans-6e-triphenyl-4-phosphorinanone 1-sulfide
Palladium-catalyzed three carbon chain extension reactions with acrolein acetals. A convenient synthesis of conjugated dienals
Evidence for the effect of a reversed micelle on the transition state for the hydration of 1,3-dichloroacetone
Free-radical and anion intermediates in the reactions of 5-halo-2-norbornenes and 3-halonortricyclenes with (trimethyltin)sodium
Stereoselective bromination of allylic alcohols. A facile synthesis of (E)- or (Z)-bromo epoxides from a common starting material
Quantum efficiencies of the cis/trans photoisomerization of protonated .alpha.,.beta.-unsaturated carbonyl compounds
Total synthesis of dl-ancistrofuran: a study of cyclic ether formation
Intramolecular anionic cycloaddition of 1-(3-phenyl-2-propenyl)-4-piperidinecarbonitrile. Synthesis of the 2,4a-ethanobenz[g]isoquinolin-5(1H)-one ring system
2,4-Dinitrophenyl dihydrogen phosphate: a new synthesis of its mono-2,6-lutidinium salt
Stereoselective chiral synthesis of N-aryl-.alpha.-amino-.beta.-lactams from .beta.-hydroxy-.alpha.-amino acids
Masthead
A mild and convenient conversion of ketones to the corresponding methylene derivatives via reduction of tosylhydrazones by bis(benzoyloxy)borane
gem-Dimethyl effect in a Grignard reagent cyclization-cleavage rearrangement
Polyether-based triphase catalysts. A synthetic comparison
(2S,3S,4R)-4-Amino-3-hydroxy-2-methylvalerate. Synthesis of an amino acid constituent of bleomycin from L-rhamnose
Diterpenes from the sponge Dysidea amblia
Palladium-catalyzed synthesis of 2,4-dienoic acid derivatives from vinylic halides
Photochemical addition of tertiary amines to stilbene. Stereoelectronic control of tertiary amine oxidation
Isolation and structure determination of piptocarphins A-F, cytotoxic germacranolide lactones from Piptocarpha chontalensis
Allergenic .alpha.-methylene-.gamma.-lactones. General method for the preparation of .beta.-acetoxy- and .beta.-hydroxy-.alpha.-methylene-.gamma.-butyrolactones from sulfoxides. Application to the synthesis of a tuliposide B derivative
Hydrolysis of esters and amides in strongly basic solution. Evidence for the intermediacy of carbanions
o-Benzoylbenzoic acids by the reaction of lithium 2-lithiobenzoates with acid chlorides. A contribution to the chemistry of alizarin and podophyllotoxin
Microbial stereodifferentiating reduction of 2,6-adamantanedione and hexahydrodibenzoheptalene-5,11-dione, diketones with two homotopic carbonyl groups on a C2 symmetry axis
Carbon-phosphorus heterocycles. Synthesis and conformational analysis of alkyl-substituted 1,2,6-triphenyl-4-phosphorinanones and derivatives
Reduction of alkyl halides by sodium naphthalene: proton sources
Substituent effects on the product distribution in diazo amide photochemistry. Role of ground-state conformational populations
Synthesis and carbon-13 nuclear magnetic resonance studies of .DELTA.5 saturated 4,4-disubstituted 3-ketosteroids
Preparation of (R)-(+)- and (S)-(-)-4-iodo-1,2-epoxybutane [(R)- and (S)-(2-iodoethyl)oxirane], useful chiral synthons
Thermal rearrangement of a 2-methylenebicyclo[2.1.1]hexane
Synthesis and properties of two dioxadioxoparacyclophanes
New synthesis of .alpha.-alkylamino ketones
Directed dilithiation of hexafluorocumyl alcohol - formation of a reagent for the facile introduction of a stabilizing bidentate ligand in compounds of hypervalent sulfur (10-S-4), phosphorus (10-P-5), silicon (10-Si-5), and iodine (10-I-3)
Synthesis and reactions of spirooxiranes in the 6,5'-cyclopyrimidine nucleoside series: preparation of 5'-deoxy-5'-(hydroxymethyl)-6,5'(S)- and -6,5'(R)-cyclouridines
Analysis of the proton nuclear magnetic resonance spectrum of 11.beta.-hydroxyprogesterone by one- and two-dimensional methods. Some implications for steroid and terpenoid chemistry
Aromatization of arene 1,2-oxides. 1,2-Oxides of methyl phenylacetate and methyl trans-cinnamate
Deuterium isotope effects in carbon-13 nuclear magnetic resonance spectroscopy. Investigation of tautomeric equilibriums in enamino ketone systems
Photochemical reactivity of keto amidines. Type I rearrangement to aminocyclopropyl isocyanates and photochemical generation of bisisocyanates from bichromophoric systems
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