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The tertiary amide as an effective director of ortho lithiation
Useful synthesis of .alpha.,.beta.-dehydrotryptophan derivatives
Electrooxidative cleavage of carbon-carbon linkages. 1. Preparation of acyclic oxoalkanoates from 2-hydroxy- and 2-acetoxy-1-cycloalkanones and cycloalkanone enol acetates
Formation of novel phospha(PV)azenes via a redox condensation process between phosphorus(III) compounds and azodicarbonamide
Acid hydrolysis of carboxylic esters in a two-phase system in the presence of catalytic amounts of quaternary onium salts. Mild and selective cleavage of tert-butyl esters
Deoxygenation of 7-oxabicyclo[2.2.1]hepta-2,5-diene systems to substituted benzenes by titanium tetrachloride-lithium aluminum hydride
Metabolites of four nudibranchs of the genus Hypselodoris
Synthesis with .alpha.-heterosubstituted phosphonate carbanions. 12. X-ray structure determination of (R,S)-diphenyl 1-(4-bromoanilino)-1-(4,5-methylenedioxy-2-nitrophenyl)methanephosphonate
Hydrogen bonded complexes. 3. Some anomalous acid salts of dibasic acids
Photostimulated reaction of diphenylarsenide and diphenylstibide ions with haloaromatic compounds by the SRN1 mechanism. Electron transfer vs. bond breaking of the radical anion intermediate
Pteridines. 49. Synthesis of 2,4-diamino-6,8-dihydro-7-aryl-8-oxopyrrolo[3,4-g]pteridines
Evidence for proton tunneling in strong base promoted (stepwise) .beta.-elimination reactions
Identification of minor products from oxymercuration-demercuration of bullvalene: substituent effects on mechanisms of free-radical rearrangements
Acid-catalyzed carbon monoxide insertion in tert-alkyl aromatics and its use for ring enlargements
Oxidation of thiols by nitric oxide and nitrogen dioxide: synthetic utility and toxicological implications
Monobactams. Stereospecific synthesis of (S)-3-amino-2-oxoazetidine-1-sulfonic acids
Hyperconjugation as a parameter in correlation analysis
Benzo[c]phenanthrene and its oxidized metabolites
Germacranolides of Inula eupatorioides. 2. Absolute configuration of the ineupatorolides
Stable peroxides from chlorine-photosensitized oxidation of perchlorinated olefins
Permanganate ion oxidations. 14. Kinetics and mechanism of the oxidation of aliphatic aldehydes in acid media
Carbon-13 NMR chemical shifts of chlorinated and fluorinated phthalic anhydrides and acids
Micellar inhibition of the neutral hydrolysis of 3-substituted 1-benzoyl-1,2,4-triazoles. Microenvironmental effects at the surface of SDS and CTAB micelles
Hypocholesteremic agent compactin (ML-236B). Total synthesis of the hexahydronaphthalene portion
Lewis acid mediated reactions of organocopper reagents. Entrainment in the conjugate addition to .alpha.,.beta.-unsaturated ketones, esters, and acids via the RCu.cntdot.BF3 system
Trans-2-(2-propenyl)-1-(2-methyl-1-propenyl)cyclopropane (rothrockene). A non-head-to-tail monoterpenoid with a new skeletal system from Artemisia tridentata rothrockii
Masthead
New penem synthesis via a novel pummerer rearrangement process
Stereochemistry of deconjugative alkylation of ester dienolates. Stereospecific total synthesis of the litsenolides
Thermal isomerizations of cis- and trans-2,2-difluoro-3-methyl-1-vinylcyclopropane
Protected lactam-bridged dipeptides for use as conformational constraints in peptides
Oxidations of thio ketones by singlet and triplet oxygen
Carbon-13 NMR as a probe for the structural assignment of 1,4,5-trisubstituted imidazoles
Regioselective alkylation of anthrahydroquinone and anthrone in water with quinonemethides and other alkylating agents
Stereoselective control in the alkylation and annelation of anions and dianions derived from 5-norbornene-2,3-dicarboximides
Steric, polar, and resonance effects in reactivity and regioselectivity of aryl radical addition to .alpha.,.beta.-unsaturated carbonyl compounds
Organoborates: carbonylation, cyanoborate, and alkynylborate processes. Energetics of sequential 1,2-shifts from boron to carbon calculated by ab initio and MNDO methods
Corticoid synthesis via vinylic fluoride-terminated biomimetic polyene cyclizations
Structural effects in solvolytic reactions. 39. Examination of the ability of the carbon-13 NMR shift-.sigma.C+ correlation for substituted benzylic cations to accommodate the highly electron donating 5-coumaranyl moiety. Evaluation of the significance of the .rho.C+ values observed for the simple aryldialkyl carbocations
Syntheses and conformational analyses of isomeric cocaines: a proton and carbon-13 NMR study
Spectral evidence of .pi.-.pi. sandwiching of aromatic rings in 10-benzylanthrones
Metallo aldimines. 3. Coupling of lithium aldimines with aryl, vinyl, and acetylenic halides
Crown cation complex effects. 16. Solvent dependence of the 15-crown-5 and 18-crown-6 equilibriums with sodium cation
Asymmetric synthesis of five- and six-membered lactones from chiral sulfoxides: application to the asymmetric synthesis of insect pheromones, (R)-(+)-.delta.-n-hexadecanolactone and (R)-(+)-.gamma.-n-dodecanolactone
Periselective cycloaddition of tricarbonyliron complexes of seven-membered unsaturated compounds with 1,2,4,5-tetrazine. Masking and activating effects of tricarbonyliron complexes
New procedure for the transformation of alcohols to alkyl halides via xanthate esters and free-radical intermediates
2-[(Acylamino)methyl]-6-methylpyrimidin-4(3H)-ones. Novel precursors for the synthesis of imidazo[1,5-a]pyrimidines and imidazo[4,5-b]pyridines
A stereospecific synthesis of trisubstituted alkenes via hydridation of dialkylhaloboranes followed by hydroboration-iodination of internal alkynes
Cathodic reductions of aroyl chlorides
The nucleophilicity of nitranions
Monobactams. The conversion of 6-APA to (S)-3-amino-2-oxoazetidine-1-sulfonic acid and its 3 (RS)-methoxy derivative
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