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On the mechanism of the conversion of dethiobiotin to biotin in E. coli. Studies with deuterated precursors using tandem mass spectroscopic (MS-MS) techniques
Preparation and rearrangement of 1,2-dialkenylcyclobutanols. A useful method for synthesis of substituted cyclooctenones
Synthetic applications of 2-cyano-1,2,3,6-tetrahydropyridines. Improved synthesis of the fundamental tetracyclic framework of dasycarpidone
Synthesis of .alpha.-phenylthio aldehydes and alkylation of 2-(phenylthio)octanal enolate
Synthesis of fluorinated acetylenes
Further studies on the synthesis of thienamycin: a facile and stereoselective synthesis of a bicyclic .beta.-keto ester by 1,3-dipolar cycloaddition
Studies on the syntheses of heterocyclic and natural compounds. 950. Asymmetric total synthesis of (+)-chenodeoxycholic acid. Stereoselectivity of intramolecular cycloaddition of olefinic o-quinodimethanes
Total synthesis of racemic triptolide and triptonide
Benzo[b]thiophene S-oxides and related compounds from the reactions of arylalkynes and antimony pentafluoride in sulfur dioxide
Nitrolysis of dialkyl tert-butylamines
.gamma.-Alkoxyallylboronates as useful reagents for preparation of differentially protected diol derivatives
Photochemistry of vinyl halides. Vinyl cation from photolysis of 1,1-diaryl-2-halopropenes
Stereoselectivities in methylcyclopropanations of cycloalken-3-ols with ethylidene iodide using zinc dust-cuprous chloride or diethylzinc reagents
Oxidation of ionol by silver(I)
Oxygenation of 2,6-di-tert-butylphenols bearing an electron-withdrawing group in the 4-position
Substituent effects. 9. Two charged groups. Remarks on the Eucken/Kirkwood-Westheimer model and the reversed-field effect
New synthesis of diazepam and the related 1,4-benzodiazepines by means of palladium-catalyzed carbonylation
Kinetics and some equilibriums of transacylation between oxy anions in aprotic solvents
2-Benzazepines. I. Synthesis of 2-benzazepin-4-ones and -5-ones via 2-acetylenic benzophenones
Synthesis and properties of halohydroxyacetones and halomethylglyoxals
Prostaglandins. 3. Synthetic approaches to 11-deoxyprostaglandins
Benzocyclobutenones as synthons for the synthesis of C-11 oxygenated diterpenoids. Application to the total synthesis of (.+-.)-taxodione
Routes to mitomycins. Application of iminium salts to the synthesis of 7-methoxymitosene
Studies in the elimination of substituted vinyl halides to acetylenes
Botryodiplodin, a mycotoxin synthesized by a strain of P. roqueforti
Synthesis of stereoisomeric crown ethers composed of cis- and trans-2,5-bis(hydroxymethyl)tetrahydrofuran units and their selective transport of alkali metal cations through liquid membranes
.sigma.-Naphthoquinodimethanes and .sigma.-phenanthroquinodimethanes. Isoindene-related species
Decarbonylation of aroyl fluorides using Wilkinson's catalyst: a reevaluation
Reactivity of 2-ethoxy-5-alkyl-3,4-dihydro-2H-pyrans toward aluminum alkyls: stereoselective preparation of cyclobutyl derivatives
Structural effects in amides. Crystal and molecular structures of phosphoric and carboxylic anilides
Poly(ethylene glycols) are extraordinary catalysts in liquid-liquid two-phase dehydrohalogenation
Determination of addition rates of thiyl radicals to vinyl monomers by means of flash photolysis. 8. Polar effect in addition rates of substituted benzenethiyl radicals to .alpha.-methylstyrene determined by flash photolysis
Isoxazolines by cycloadditions of mesitonitrile oxide with benzo[b]thiophene S-oxide and S,S-dioxide. Structural studies, theoretical explanations, and kinetics
Stereoselective ketone reductions: reduction of 4-tert-butylcyclohexanone by alkylsilanes in the presence of rhodium(I) and ruthenium(II) catalysts
Palladium-promoted intramolecular aromatic nuclear acyloxylation: preparation of 2-coumaranone
NB-Enantride, a new chiral trialkylborohydride for the asymmetric reduction of ketones
Normal SNAr, telesubstitution, and electron-transfer pathways in the reactions of methyl-substituted o-bis(phenylsulfonyl)benzene derivatives with sodium arenethiolates in dimethyl sulfoxide
Reactions of vinylphosphonates. 2. Synthesis of functionalized dienes, trienes, and their analogs. Synthetic applications to regioselectively functionalized benzene derivatives
Enones with strained double bonds. 7. Precursors for substituted bicyclo[3.3.1]nonane systems
Reaction of 2-(methylseleno)- and 2-(phenylseleno)benzoic acids and their derivatives with tert-butyl hydroperoxide. Neighboring selenium participation and facile formation of cyclic selenuranes and a selenurane oxide
Kinetics of the reduction of isoquinolinium cations by 1,4-dihydronicotinamides
Reductive condensation of methyl arylglyoxylates. Direct synthesis of 2,3-bis(carbomethoxy)stilbene oxides and related systems
Synthetic studies of fungal metabolites: ascofuranone and colletochlorin D
Synthesis of the (E) and (Z) isomers of the antiestrogen tamoxifen and its metabolite, hydroxytamoxifen, in tritium-labeled form
Regiochemistry of intramolecular munchnone cycloadditions: preparative and mechanistic implications
One-step .alpha.-tosyloxylation of ketones with [hydroxy(tosyloxy)iodo]benzene
Masthead
Mechanism for diacyl peroxide decomposition
Photochemistry of benzil monobenzhydrylimine
An efficient and remarkably regioselective synthesis of benzocyclobutenones from benzynes and 1,1-dimethoxyethylene
Enantiotopically selective oxidation of .alpha.,.omega.-diols with enzyme systems of microorganisms
Stereoselective synthesis via Claisen rearrangements of the marine sterols occelasterol, patinosterol, and 22,23-dihydrooccelasterol
Reaction of 2-amino-3-cyano-4-methylfuran as a dienamine and a diene
p-Methoxybenzoyl p-nitrobenzoyl peroxide revisited: catalysis by silica
Conversion of 2,4,6-trinitrobenzyl chloride to 2,2',4,4',6,6'-hexanitrostilbene by nitrogen bases
Reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals
Nonhydrated anion transfer from the aqueous to the organic phase: enhancement of nucleophilic reactivity in phase-transfer catalysis
Kinetics of the reduction of 3,4-dihydroisoquinolinium cations by 1,4-dihydronicotinamides
Synthesis of phosphorins by reaction of 1,2,5-triphenylphosphole with alkynes
Competing .beta.-fragmentation in regeneration of alcohols from arenesulfonates with arene anion radicals
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