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Hydroxymethyl derivatives of 18-crown-6 and [2.2.2]cryptand: versatile intermediates for the synthesis of lipophilic and polymer-bonded macrocyclic ligands
A novel, nonoxidative method for the conversion of aldehydes to esters
Synthesis of simple derivatives of (2Z,4Z)-3-methyl-2,4-hexadienedioic acid
Sesquiterpene synthesis. Studies relating to the synthesis of (.+-.)-dugesialactone
Synthesis of chiral dipeptides by means of asymmetric hydrogenation of dehydro dipeptides
Ring forming reactions: adjustable regiocontrol on a polyfunctional substrate
Sulfoximine-mediated syntheses of optically active alcohols
Electrochemistry of carbonium ions in acidic media. 1. Triphenylmethyl ion in aluminum chloride containing melts
Origins of regio- and stereoselectivity in additions of phenylselenenyl chloride to allylic alcohols and the applicability of these additions to a simple 1,3-enone transposition sequence
Proton nuclear magnetic resonance analysis for meso and DL isomers of succinic-d2 acid
Total synthesis of carbohydrates: stereoselective syntheses of 2,6-dideoxy-D-arabino-hexose and 2,6-dideoxy-D-ribo-hexose
Synthesis of saccharides and related polyhydroxylated natural products. 2. Simple deoxyalditols
Substituent parameter analysis of the carbon-13 nuclear magnetic resonance chemical shifts 4-substituted p-terphenyls
Isolation and structural elucidation of zoapatanol and montanol, novel oxepane diterpenoids from the Mexican plant zoapatle (Montanoa tomentosa)
Studies in biomimetic alkaloid syntheses. 8. Total syntheses of the C-14 epimeric hydroxyvincadifformines, tabersonine, a (hydroxymethyl)-D-norvincadifformine and the C-20 epimeric pandolines
Orientation in base-promoted dehydrochlorination of 2,2,3-trichlorobutane
Regioselective functionalization. 5. Nitrogen insertion reactions of bicyclo[3.2.1]octan-2-one. Reexamination of bridgehead vs. methylene migratory preferences
Solvent effect on the kinetics of the chlorine isotopic exchange reaction between chloride ion and O,O-diphenyl phosphorochloridate or O,O-diphenyl phosphorochloridothioate
Temperature-dependent acid dissociation constants (Ka, .DELTA.Ha, .DELTA.Sa) for a series of nitrogen-substituted hydroxamic acids in aqueous solution
Restricted rotation in methyldithiomethyl radical, CH3SS.ovrhdot.CH2
Dianions derived from .alpha.-halo acids. The Darzens condensation revisited
Total syntheses of (.+-.)-cerulenin, (.+-.)-tetrahydrocerulenin and related compounds
Chiral intermediates from aucubin as synthons of modified 11-methylprostaglandins. Assignment of correct structures to two tetrahydrodideoxyaucubins
New highly fluorescent derivative of adenosine. Cyclization of adenosine with 1'-methylthiaminium ion
Synthesis of saccharides and related polyhydroxylated natural products. 1. Simple alditols
Masthead
.alpha.-Nitro ketones. 6. Synthesis and conformation of 2-methyl-2-nitro-, cis- and trans-6-methyl-2-nitro-, and cis- and trans-2,6-dimethyl-2-nitrocyclohexanones
Constituents of Eremocarpus setigerus (Euphorbiaceae). A new diterpene, eremone, and hautriwaic acid
Synthesis of 2-azabenz[a]anthracene
Micellar effects upon dephosphorylation by amidoximes
Monoacylsulfuric acids as intermediates for .alpha.-halogenation of aliphatic acids
Ion binding and micellar effects upon reactions of carboxylic anhydrides and carbonate esters
Magnetic circular dichroism of cyclic .pi.-electron systems. 26. 6,7-Dihydroacenaphtho[5,6-cd][1,2,6]thiadiazine and acenaphtho[5,6-cd][1,2,6]thiadiazine
Synthesis and structural verification of novel olefinic derivatives of bicyclo[2.2.2]octane. Intermediates in the synthesis of bridged morphinan-like compounds
Stereochemical evidence for the formation of intermediates in the ene reaction of singlet oxygen with tetraalkyl-substituted alkenes
Palladium-catalyzed reactions of vinylic bromides with allylic alcohol and amine derivatives
Diastereoselective reductions of .beta.-keto Sulfoximines
Palladium-catalyzed arylation and vinylation of 1,4-dienes
Alkaloid synthesis via intramolecular ene reaction. 2. Application to dl-mesembrine and dl-dihydromaritidine
Photocyclization of 1,2-diarylethylenes in primary amines. A convenient method for the synthesis of dihydro aromatic compounds and a means of reducing the loss of methyl groups during the cyclization of o-methylstilbenes
Synthesis of 3,4-bis(alkylidene)cyclobutenes by the reductive dimerization of propargyl chlorides
Hydrolysis of aldal acetals
Preparation of chiral diphenyl substituted polyether-diester compounds
Observations on the chemistry of .alpha.-azido ester. Efficient synthesis of a potently sweet homoserine-dihydrochalcone conjugate
Reaction of trifluoroacetic acid with alcohols, phenols, ethers, and their sulfur analogs
.alpha.-Diazophosphonic acids as potential photoaffinity labeling reagents: synthesis, stability, and photochemistry
TLC mesh column chromatography
Bis(trialkylsilyl) chalcogenides. 1. Preparation and reduction of group VIA oxides
Electrochemical reduction of N-bromosuccinimide. Reaction mechanism for formation of the succinimidyl radical
Mechanism of the reaction between benzylmagnesium chloride and carbonyl compounds. A detailed study with formaldehyde
Efficient "one-pot" synthesis of N-tritylamino acids
Derivatives of the thebaine anion. 1. Structure of metopon. A direct demonstration
Retro-Diels-Alder cleavage of endo-bicyclo[2.2.1]hept-5-en-2-ol
Reactions of 3-(phenylthio)-3-buten-2-one with cycloalkanones. A new approach to fused phenols
Acylative cleavage of ethers catalyzed by triorganotin halides and palladium(II) complexes
tert-Butyllithium additions to enones. Preferential axial attack
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