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Topological correlations of carbon-13 chemical shifts by perturbation on a focus: DARC-PULFO method. Attenuation and inversion of .alpha.-methyl substituent effects
Lithium ammonia reductions of 2-thiophenecarboxylic acids
Stereocontrolled synthesis of (-)-zonarene
Regioselective synthesis of acylpyrroles
Quassinoids. 2. Synthesis of an ABCD ring precursor involving a lactonization induced by iodotrimethylsilane
Sulfur-substituted dienes and the silylene protecting group in synthesis. Deoxypillaromycinone
Coupling reactions of higher order cuprates with primary halides: extremely mild and efficient substitution reactions of bromides and chlorides
Reaction of dimethyl 3-oxoglutarate with 1,3-dicarbonyl compounds
High-yield acyl anion transfer reactions. Synthesis of acyltetrahydrofurans
Electrophilic addition of p-nitrobenzenesulfonyl peroxide to 3,4-dihydro-2H-pyran
Synthesis of carbon 1 C-.beta.-D-ribofuranosyl derivatives with a highly functionalized two-carbon unit. Conversion to certain blocked thiazole C-nucleosides
Synthesis of 7,11,12-trimethylbenz[a]anthracene
Conversion of acetals and ketals to carbonyl compounds promoted by titanium tetrachloride
Convenient synthesis of medium-ring cis-1,2-dichlorocycloalkanes
Crown ethers of low symmetry. Spiro crown ethers and 16-crown-5 derivatives
An unusual reduction of an .alpha.-oxo ester by lithium diisopropylamide
On the aprotic Robinson annelation of dihydrocarvone and 2-methylcyclohexanone with methyl and ethyl vinyl ketone
Synthesis, chemistry and photochemical substitutions of 6,11-dihydro-5H-pyrrolo[2,1-b][3]benzazepin-11-ones
A chemical model for the mechanism of vitamin K epoxide reductase
Synthesis of five-membered halo enol lactone analogs of .alpha.-amino acids: potential protease suicide substrates
A facile intramolecular tertiary amine displacement reaction
Silica gel-mediated photoisomerization of retinal isomers and comparisons with other forms of environmental perturbation
Aureolic acid antibiotics: synthesis of a model aglycon
Solvent isotope effects on the kinetics of nucleophilic addition of water to a .beta.-nitrostyrene
Photolysis of 4-diazopyrrolidine-2,3-diones. A new synthetic route to mono- and bicyclic .beta.-lactams
Synthesis of dehydrooogoniol, a female-activating hormone of Achlya
Electrochemical peak potentials of typical substrates used for coupling reactions with organocuprates: effects of solvent
Spatane diterpenoids from the tropical marine algae Spatoglossum schmittii and Spatoglossum howleii (Dictyotaceae)
Novel trialkoxymethyl disulfides via nucleophilic addition to thionocarbonates: tris(2-fluoro-2,2-dinitroethoxy)methyl trichloromethyl disulfide and related products
Decarboxylative ipso halogenation of mercury(II) pyridinecarboxylates. Facile formation of 3-iodo- and 3-bromopyridines
Kinetics and mechanism of the oxidation of alcohols by N-bromoacetamide in alkaline solution
Silica gel assisted reductive cyclization of alkoxy-2, .beta.-dinitrostyrenes to alkoxyindoles
Silanes in organic synthesis. 19. Examination of (-)-.alpha.-naphthylphenylmethylallylsilane as a template for effecting chirality transfer from silicon to carbon
Synthetic methods and reactions. 91. Ionic fluorination of adamantane, diamantane, and triphenylmethane with nitrosyl tetrafluoroborate/pyridine polyhydrogen fluoride (PPHF)
Preparation of nonsymmetrical p-benzoquinone diimides for evaluation as protein cleavage reagents
Synthesis and rearrangements of dihydro-1,4-oxazepine and dihydro-1,4-thiazepine derivatives
Synthesis of 4-methylene-1,3-dioxolan-2-one. A bifunctional cyclic carbonate
Boron trifluoride promoted reaction of alkyl hypohalites with alkenes. A new synthesis of fluoro halides
Dissolving-metal reduction of a hemispherical dichloro diester. Tests of relative enolate nucleophilicity within a mixed dianion and oxidative behavior of a trisecododecahedryl alcohol
Synthesis of 2-, 3- and 9-substituted 11-oxo-11H-pyrrolo[2,1-b][3]benzazepines
Facile synthesis of 5-acyl-4-amino-2-ethoxythiazoles from an [ethoxy(thiocarbonyl)]cyanamide salt and .alpha.-halo ketones
An efficient synthesis of substituted isoquinolines
Heterogeneous catalysis by solid superacids. 17. Polymeric perfluorinated resin sulfonic acid (Nafion-H) catalyzed Fries rearrangement of aryl esters
Application of two-dimensional FT NMR to the relative configurational assignment of 8-methyl-4-oxo-10-(trimethylsiloxy)tetracyclo[7.2.1.02,8.03,7]dodecane-10-carbonitrile
Catalytic replacement of unactivated alkane carbon-hydrogen bonds with carbon-X bonds (X = nitrogen, oxygen, chlorine, bromine, or iodine). Coupling of intermolecular hydrocarbon activation by MnIIITPPX complexes with phase-transfer catalysis
Isolation of the intermediates in a benzoin-type condensation
A new transformation of amines to carbonyl compounds
Masthead
Syntheses of ethyl retinoate with polymer-supported Wittig reagents
Utilization of vinylsilanes in [4+2]-cycloaddition reactions
Synthetic approaches to rhodomycinone and olivin
Long-lived trialkylhydroxylamine and N-acyldialkylhydroxylamine radical cations
Studies on the syntheses of heterocyclic compounds and natural products. 999. Double enamine annelation of 3,4-dihydro-1-methyl-.beta.-carboline and isoquinoline derivatives with 6-methyl-2-pyrone-3,5-dicarboxylates and its application for the synthesis of (.+-.)-camptothecin
Synthesis of sugars by aldolase-catalyzed condensation reactions
A theoretical study of 1-2, 1-3, and 1-4 hydride shifts in the cyclohexyl cation
Synthetic methods and reactions. 121. Zinc iodide catalyzed preparation of aroyl azides from aroyl chlorides and trimethylsilyl azide
Syntheses of 9-(trifluoromethyl)- and 10-(trifluoromethyl)-7,12-dimethylbenz[a]anthracenes
Electrochemical reduction of 1-iodo-5-decyne and 1-bromo-5-decyne at mercury cathodes in dimethylformamide
Catalysis by solid superacids. 18. Nafion-H perfluorinated resin sulfonic acid promoted deacetylation and decarboxylation of aromatics
Carbanion-accelerated Claisen rearrangements. 2. Studies on internal asymmetric induction
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