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Synthesis and conformational aspects of cis- and trans-3-carbomethoxy-6-oxabicyclo[3.1.0]hexane
Masthead
Total synthesis of oleandrose and the avermectin disaccharide, benzyl .alpha.-L-oleandrosyl-.alpha.-L-4-acetoxyoleandroside
The sipholanes, a novel group of triterpenes from the marine sponge Siphonochalina siphonella
Highly chemoselective reductions with polymethylhydrosiloxane and palladium(0) catalyst
Chiral ether glycerides from a marine sponge
Preparative reversed-phase flash chromatography, a convenient method for the workup of reaction mixtures
Study of substituent effects on one-bond carbon-13-carbon-13 NMR coupling constants in adamantane derivatives.
A simple and efficient synthesis of chiral acetic acid of high optical purity
Ant-repellent triterpenoids from Cordia alliodora
Bis(methoxycarbonyl)sulfur diimide, a convenient reagent for the allylic amination of alkenes
Assignment of the high field resonances of a gorgosterol derivative through the use of autocorrelated two-dimensional proton NMR spectroscopy
Resolution of chiral alcohols with mandelic acid
Efficient method for a one-carbon homologation of aldehydes and benzophenone to carboxylic acids
Short synthesis of bicyclo[3.2.2]nona-3,6,8-trien-2-one
Practical multigram synthesis for 4(5)-vinylimidazole
Application of spin-echo techniques to the determination of 13C labeling using proton NMR spectroscopy
Stereoselective reductions of substituted cyclohexyl and cyclopentyl carbon-nitrogen .pi. systems with hydride reagents
Stereoselective synthesis of (5E)- and (5Z)-vitamin D3 19-alkanoic acids via vitamin D3-sulfur dioxide adducts
An efficient synthesis of 2-methyl-4-hydroxy-2H-1,2-benzothiazine 1,1-dioxides
Kinetic resolution of racemic .beta.-hydroxy amines by enantioselective N-oxide formation
Reaction of methyl 4-bromocrotonate with lithium ester enolates: direct SN2 displacement vs. Michael-initiated ring closure
Temperature dependence of the kinetic isotope effect in the homolytic abstraction of benzylic hydrogen by bromine
Structural effects in solvolytic reactions. 44. Effect of increasing electron demand on the carbon-13 NMR shifts in 1-aryl-1-hydroxyethyl carbocations. Deviations in the .sigma.C+-.DELTA..delta.C+ plot for these protonated acetophenones containing strongly electron-withdrawing substituents
Synthesis applications of cationic aza-Cope rearrangements. Part 13. Stereoselective synthesis of cis- and trans-3a-aryl-4-oxodecahydrocyclohepta[b]pyrroles
Studies directed toward the total synthesis of securinega alkaloids
Liquid crystalline solvents as mechanistic probes. 11. The syn .fwdarw. anti thermal isomerization mechanism of some low-bipolarity azobenzenes
Cyclic sulfur esters as substrates for nucleophilic substitution. A new synthesis of 2-deoxy-2-fluoro-D-glucose
Chiral synthesis of protected 3-amino-4-(alkoxycarbonyl)-2-azetidinones from .beta.-hydroxyaspartic acid
Host-guest binding capacity of cucurbituril
Studies on the preparation and reactions of tritylsulfenimines
Influence of steric effects upon the rate constants for competing BAC2 and E1cB ester hydrolyses
Facile syntheses of aldehydes and .beta.-dialdehyde monoacetals
Cycloaddition induced by cucurbituril. A case of Pauling principle catalysis
Substituent effect on the electrochemical oxidation of arylmethyl anions. 3. Effect of methyl substitution on diarylmethyl anions
Chemical and enzymatic syntheses of 6-deoxyhexoses. Conversion to 2,5-dimethyl-4-hydroxy-2,3-dihydrofuran-3-one (Furaneol) and analogs
Practical procedure for the isolation of emodin and chrysophanol
Onium ions. 27. Oxidation of sulfoxides to sulfones with nitronium salts
Stereopopulation control. 9. Rate and equilibrium enhancement in the lactonization of (o-hydroxyphenyl)acetic acids
C(12)-Substituted prostaglandins. An enantiospecific total synthesis of (+)-12-fluoromethylprostaglandin F2.alpha. methyl ester
Marine toxins of Latrunculia magnifica
Improved synthesis of selenophene
Reactions of 2-anti-hydroxy-4-aza-5-homoadamantan-5-one
Two topologically distinct total syntheses of (.+-.)-sarkomycin
Stereospecific 2 + 2 + 2 annulation
Hydrolysis, nitrosyl exchange, and synthesis of alkyl nitrites
Penicillin-cephalosporin conversion. VIII. Synthesis of 2,3'-bisthio-substituted cephalosporins via electrolytic chlorination of thiazolinoazetidinone
Kinetic studies on the formation and decay of some sulfonium radicals
Regiospecific electrophilic substitution of aminopyridines: ortho lithiation of 2-, 3-, and 4-(pivaloylamino)pyridines
Synthesis of 10-(chloromethyl)benzo[a]pyrene
Phthalide annulation: the synthesis of kalafungin, pachybasin and chrysophanol
Reaction of 1-nitroso-1,2,3,4-tetrahydropyridine with mineral acids
Esterification using a polymer-supported phosphine reagent
Synthesis and solution dynamics of agrobactin A
Structures and relative energies of silabenzene isomers
Identification of configurational isomers of Fluorochloridone
Silicon-mediated synthesis of 11-deoxyanthracyclines
Synthetic applications of heteroatom-directed photoarylation. Benzo[b]furan ring construction
Formation of hydroxy radicals from radical cations of some substituted benzenes in aqueous solutions at 80.degree.C and at room temperature. Effect of oxygen
Studies on the development of the tritylsulfenyl group as a nitrogen protecting group and application in a synthesis of .delta.-coniceine
Persulfate/silver ion decarboxylation of carboxylic acids. Preparation of alkanes, alkenes, and alcohols
Cycloaddition. 30. Synthesis, regiochemistry, and reactions of dichlorocyclobutenones
Sterols in marine invertebrates. Part 42. Isolation, partial synthesis and structure determination of sterols with the four possible 23,24-dimethyl-substituted side chains
Studies of vitamin D oxidation. 3. Dye-sensitized photooxidation of vitamin D and chemical behavior of vitamin D 6,19-epidioxides
Synthesis of di-tert-butyl methylenemalonate, a sterically hindered 1,1-dicarbonyl alkene
Initial products in Friedel-Crafts reactions
Intramolecular cyclopentene annulation. 3. Synthesis and carbon-13 nuclear magnetic resonance spectroscopy of bicyclic cyclopentene lactones as potential perhydroazulene and/or monoterpene synthons
Quantitative removal of a pentadecapeptide ACTH fragment analog from a Merrifield resin using ammonium formate catalytic transfer hydrogenation: synthesis of [Asp25,Ala26,Gly27,Gln30]-ACTH-(25-39)-OH
Improved synthesis and absolute configuration of (+)- and (-)-2,2,4-trimethyl-1,3-dioxolane-4-carboxaldehyde
Anhydrous tert-butyl hydroperoxide in toluene: the preferred reagent for applications requiring dry TBHP
Phosphine- and phosphite-mediated difluorocarbene exchange reactions of (bromodifluoromethyl)phosphonium salts. Evidence for facile dissociation of (difluoromethylene)triphenylphosphorane
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