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Studies in the 2,4-disubstituted adamantanes. Preparation and reactivity of pure epimeric 4-hydroxy- and 4-methoxyadamantan-2-ones
Aromatic fluoroalkoxylation via direct aromatic nucleophilic substitution
Regioselective hydroesterification and hydrocarboxylation of 3,3,3-trifluoropropene and pentafluorostyrene catalyzed by phosphine-palladium complex
1,3,4-Dioxazol-2-ones: a potentially hazardous class of compounds
Influence of alkoxyalkyl substituents in the regioselective lithiation of the benzene ring
Thermolysis of 3-methyl-3-alkyl-1,2-dioxetanes: steric effects on the activation parameters
Preparation of alkyl chlorides, acid chlorides, and amides using polymer-supported phosphines and carbon tetrachloride: mechanism of these reactions
Transition from concerted to stepwise [2 + 4] cycloaddition reactions of .alpha.,.beta.-unsaturated carboxylic esters
Regioselectivity of 1,3-dipolar cycloadditions of (phenylsulfinyl)- and (phenylsulfonyl)alkenes
An improved procedure for the Blaise reaction: a short, practical route to the key intermediates of the saxitoxin synthesis
Total syntheses of (.+-.)-mesembrine, (.+-.)-joubertinamine, and (.+-.)-N-demethylmesembrenone
Novel synthesis of the pyrrolizidine skeleton by sulfenocycloamination. Total synthesis of (.+-.)-retronecine and (.+-.)-turneforcidine
Total synthesis of (-)-vertinolide. A general approach to chiral tetronic acids and butenolides from allylic alcohols
Additions of organolithium compounds to unsaturated tertiary amines
High pressure [4 + 2] cycloaddition of dichloromaleic anhydride and furan
Organic metals. Preparation and properties of 7,7,8,8-tetracyano-p-quinodimethaneacetic and -propanoic acids
Efficient synthesis of barbaralane
A new olefin synthesis. Synchronous elimination of nitro and ester groups or nitro and keto groups from .beta.-nitro esters or .beta.-nitro ketones
An approach to the cyclopeptide alkaloids (phencyclopeptines) via heterocyclic diamide/dipeptide equivalents. Preparation and N-alkylation studies of 2,4(5)-disubstituted imidazoles
Reactions of arenesulfonyl chlorides with olefins catalyzed by a ruthenium(II) complex
A synthesis of oxazolo[4,3-a]isoquinoline and related compounds through intramolecular arylation of .alpha.-oxaacyliminium ions
Synthetic methods and reactions. 112. Synthetic transformations with trichloromethylsilane/sodium iodide reagent
Crystal structure of orthosphenic acid
O-Quinonemethide intermediates and their role in coordinated reactions of magnesium phenoxides with .alpha.-branched aliphatic aldehydes
Reaction of (acyloxy)alkyl .alpha.-halides with phenols: effect of nucleofugicity and nucleophilicity on product distribution
2-Mercapto-1,3-benzoxazole: an useful reagent for the preparation of symmetrical and unsymmetrical sulfides
Synthesis of 6-bromo- and 6-chloro-2-acetamidobenzoquinone. A structure revision
The [1 + 4] cycloaddition of isocyanides with 1-aryl-2-nitro-1-propenes. Methyl 2-nitro-3-arylpropenoates and methyl 2-nitro-2,4-pentadienoates. Synthesis of 1-hydroxyindoles and 1-hydroxypyrroles
Syntheses of [22](1,4)cyclophane-ruthenium(II) complexes via the mono-Birch reduction product of 4,5,7,8-tetramethyl[22](1,4)cyclophane
Peroxy esters. 8. Base-catalyzed rearrangement of peroxy esters: formation of alkoxyacetic acid derivatives
Fragmentation of metalated primary amines having tertiary organic groups
Further characterization of the 1,1-diphenyl-2,2-dimethylpropyl radical
Photoelectron spectra of syn- and anti-sesquinorbornene. Evidence for vertical .sigma.-.pi. delocalization in bicyclo[2.2.1]heptene
Neighboring group participation in organic redox reactions. 8. Kinetics and products of the aqueous iodine oxidation of 3-hydroxy- and 3-methoxy-1,5-dithiacyclooctane
Inert carbon free radicals. 4. Spin labeling of amino acids and peptides
Synthesis and transformation of certain pyridazine cyclonucleosides
Transfer hydrogenation of furocoumarin derivatives
Catechol monoether synthesis
Stereocontrolled synthesis of (E)- and (Z)-3-deuteriophosphoenolpyruvate
Masthead
Reactivity of superoxide ion with ethyl pyruvate, .alpha.-diketones, and benzil in dimethylformamide
Effect of the leaving group and solvent in nucleophilic aliphatic substitutions promoted by quaternary onium salts
Electrophilic addition of osmium tetroxide to 25-hydroxycholecaliferol and its 3,5-cyclo derivative
Photochemistry of benzyl sulfite
(Arene)chromium tricarbonyl complexes in organic synthesis: stereoselective synthesis of cis- and trans-7-hydroxycalamenenes
Total synthesis of the lipid-altering and antiatherosclerotic furochromone khellin. The furoic acid route to highly functionalized benzofurans
Reaction of organic anions. Part 108. On the mechanism of the vicarious nucleophilic substitution of hydrogen in nitroarenes
Synthetic intermediates potentially useful for the synthesis of tetrodotoxin and derivatives. 8. A series of highly functionalized pyrimidinones
Formation of dihydrotriphenodioxazines and dihydroisotriphenodioxazines by acidic treatment of some substituted 3H-phenoxazin-3-ones; isolation and characterization. A new perspective in the chemistry of ommochromes
Peroxy esters. 9. Base- and radical-induced decomposition of 1-alkyl-3,5-di-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoates
Photochemical behavior of 2-phenylbenzoxazole. Synthesis of 1,3-diazetidine via the intermolecular [2.pi. + 2.pi.] cycloaddition of two carbon-nitrogen double bonds
A new, effective catalytic system for epoxidation of olefins by hydrogen peroxide under phase-transfer conditions
A new strategy for the synthesis of spiro ketals
Diastereoselective .alpha. allylation of secondary and tertiary thioamides via thio-Claisen rearrangement. A structural proof of Z secondary thioamide dianions and Z tertiary thioamide anions
Decomposition rates, synthesis, and spectral properties of a series of alkyl hyponitrites
Allylstannanes. Synthesis, structure, and reactions of 2-methylene-1,3-propanediylbis[trimethylstannane] and -[triphenylstannane]
Microbial hydroxylation of heteroyohimbine alkaloids
Catalysis of .alpha.-hydrogen exchange. Part 23. Six-at-once dedeuteration of acetone-d6 in the presence of 3-exo-[(dimethylamino)methyl]-2-exo-norbornanamine
The two hydrogen-oxygen bond-dissociation energies of hydroquinone
Synthetic intermediates potentially useful for the synthesis of tetrodotoxin and derivatives. 9. Hydroquinazolines possessing the carbon skeleton of tetrodotoxin
Ene reactions of 2-phosphonoacrylates
Relative stabilization of an iminium ion by the charge-transfer interaction of arylthio groups
Ene-ene-retroene conversion of (-)-.beta.-pinene to (+)-.beta.-selinene
Thermal rearrangement of allenyl ketones
Hydroboration kinetics. 9. Kinetics and mechanism of the complex formation of 9-borabicyclo[3.3.1]nonane dimer with representative amines. Effect of steric hindrance on the reaction mechanism
Ultrasound in organic synthesis. 4. A simplified preparation of diarylzinc reagents and their conjugate addition to .alpha.-enones
A new variant of the Claisen rearrangement capable of creating the bond between two quaternary centers
1-Phenyl-cis-3a,7a-dihydrophosphindole and its properties
Quinolizidine alkaloid synthesis via the intramolecular imino Diels-Alder reaction. epi-Lupinine and cryptopleurine
Homolytic substitution at furan and thiophene: rate constants for the formation and decay of the radical intermediates
Transformations of cyclopropanol intermediates. 5. Preparation and reactions of 1-hydroxy-1,5.alpha.-cyclocholestan-7-one
Reversible reaction between cyclic phosphonite and aromatic cyclic disulfide to form a spiro dithiophosphorane. Observation of reductive elimination of a phosphorus(V) compound
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