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The metal-ammonia reduction of 1-acetylnaphthalenes
Mechanism of acylation of dilithium salts of .beta.-keto esters: an efficient synthesis of anibine
Studies on vitamin D (calciferol) and its analogs. Part 26. Effect of seven-membered ring fusion on thermal pericyclic processes of vinylallenes and other seco steroids related to A-homovitamin D
Crystal structure and stereochemistry of achalensolide, a new guaianolide from Stevia achalensis
Oxidative decyanation of benzyl and benzhydryl cyanides. A simplified procedure
Total synthesis of (.+-.)-sarubicin A (U-58,431)
Alkylation of allylic derivatives. 7. Stereochemistry of alkylation of the isomeric trans-.alpha.,.gamma.-methyl(phenyl)allyl acetates with lithium dialkylcuprates and alkylcyanocuprates
Reductive cleavage of aryl oxazolines to benzaldehydes and substituted toluenes
Photolytic generation of anti-Bredt imines from 1-azidobicyclo[2.2.2]octane, 1-azidobicyclo[3.3.1]nonane, and 3-azidonoradamantane
Preparation of Grignard reagents from 3-halo ethers
Iodine chloride as an intermediate for .alpha. iodination of aliphatic acids with iodine-thionyl chloride
Structure of the antibiotic cyanobacterin, a chlorine-containing .gamma.-lactone from the freshwater cyanobacterium Scytonema hofmanni
Reaction of bis(trifluoromethyl)aminoxyl with cyclopropane
A simple photochemical conversion of perfluoroalkyl hydrides to perfluoroalkyl bromides using interhalogen compounds
Direct, regiospecific 2-lithiation of pyridines and pyridine 1-oxides with in situ electrophilic trapping
Ketal Claisen rearrangements of simple aliphatic ketals
Mechanism of the iron(III)-catalyzed peracetic acid oxidation of catechol. A biomimetic reaction for pyrocatechase
The four-membered-ring chemical shift anomaly
Gas-liquid phase-transfer catalysis: catalytic and continuous transesterification reaction
Nucleophilic aromatic substitution by 3-amino-2-butenoates
Copper(I)-catalyzed reactions of .beta.,.gamma.-epoxy alcohols with Grignard reagents
Stereocontrol in the intramolecular Diels-Alder reaction. 5. Preparation of a tetracyclic intermediate for ikarugamycin
Reactions of azines. 6. Thermal rearrangements of 1,1-disubstituted-2,3-diaza-4-methyl-1,3,5,6-heptatetraenes to 4,9-dihydropyrazolo[1,5-b]isoquinolines and side products
Stereochemical kinetics of the thermal stereomutations of 1-cyano-2-phenyl-1,3-dideuteriocyclopropanes
Synthesis of the major pheromonal component of the Monarch butterfly (Danaus plexippus) via palladium-catalyzed 1,4-functionalization of isoprene
Ring-closure reactions. 21. Intramolecular .beta.-elimination competing with ring formation from o-(.omega.-bromoalkoxy)phenoxides over a wide range of ring sizes
Addition of piperidine to some 2-alkylbenzo[b]thiophene 1,1-dioxides
.DELTA.16,17-Dehydroheroinium chloride: synthesis and characterization of a novel impurity detected in illicit heroin
Site of attack of a carbene on alkylbenzenes, naphthalene, and thiophene and the norcaradiene-cycloheptatriene equilibration
Synthesis of 4-(acylacetyl)-1-phenyl-2-pyrazolin-5-ones from 3-acyl-2H-pyran-2,4(3H)-diones. Their synthetic applications to functionalized 4-oxopyrano[2,3-c]pyrazole derivatives
Stereochemistry and mechanism of chlorotelluration of olefins
Formation of 2,4-diaroyl-3,5-diarylthiolanes from chalcones and polysulfide. Scope, conditions, and the thiolane NMR
Palladium-catalyzed carbonylation. A new synthesis of .alpha.-methylene .gamma.-, .delta.-, .epsilon.-lactams and lactones including bicyclic lactams of pyrrolizidine and indolizidine skeletons
Cleavage of silicon-nitrogen bonds by acid chlorides: an unusual synthetic route to amides
Synthetic studies on sequences of vitamin K dependent proteins. Gla-Arg-Gla sequences
Photoadducts of 1-cyclohexene-1,2-dicarboxylic anhydride
A stereospecific synthesis of hydroxyl-differentiated (E)- and (Z)-1,4-enediols
Simplified method for O-alkylation of N-protected tyrosines
Dioxygenation and reduction of 2',3'-unsaturated C-nucleosides
Fluoro-decarboxylation with xenon difluoride
Palladium-catalyzed cyclizations of bromodialkenyl ethers and amines
Novel opiates and antagonists. Part 7. Diels-Alder reaction of .beta.-dihydrothebaine and its 4-phenyl ether with methyl vinyl ketone: synthesis of 6,14-exo-ethenomorphinans
Solvent dependence of the conformation and chiroptical properties of trans-9,10-dihydroxy-9,10-dihydrophenanthrene and its monoglucuronides
Metabolites from the marine sponge Tedania ignis. A new atisanediol and several known diketopiperazines
Oxidative decyanation of secondary nitriles to ketones
A one-pot conversion of olefins to .alpha.,.beta.-unsaturated carbonyl compounds. An easy synthesis of 2-cyclopentenone and related compounds
A homo-Brook rearrangement
Novel biogenetic pathways from (+)-reticuline. Three dimeric alkaloids: (+)-vanuatine, (+)-vateamine, and (+)-malekulatine
Involvement of neighboring chlorine in the exchange reactions of iodine monochloride and vicinal organic iodochlorides
Synthesis by SO2 extrusion: photochemical and thermal reactions of cinnamyl benzyl sulfone
Synthesis of adamantane derivatives. 65. Synthesis of 2-exo-hydroxy-4-thiahomoadamantane and some related derivatives
Adducts of anthrahydroquinone and anthranol with lignin model quinone methides. 3. Independent synthesis of threo and erythro isomers
Computer-assisted mechanistic evaluation of organic reactions. 7. Six electron cycloadditions
Organic photochemistry with 6.7-eV photons. The divergent photobehavior of exo- and endo-7-methyl-2-norcarene
Eliminative ring fission of 4-acyl-2,3-dihydro-4H-1,4-benzothiazines
Reaction of some azolopyrido[2,3-d]pyrimidines with active methylene compounds
Readily accessible 12-I-5 oxidant for the conversion of primary and secondary alcohols to aldehydes and ketones
Benzo[e]isobenzofuran. Formation and reactions of the parent and alkoxy-substituted derivatives
Stereoelectronic control in the aqueous decomposition of novel nitrosothioureas
Enantioselective hydrolysis of 3-hydroxy-3-methylalkanoic acid esters with pig liver esterase
Heat capacities of activation for the neutral hydrolysis of two acyl-activated esters in water-rich 2-n-butoxyethanol-water mixtures. Analysis in terms of the pseudo-phase-separation model
2,2':5',2"-Terthiophene-5-carboxylic acid and 2,2':5',2"-terthiophene-5,5"-dicarboxylic acid
Formation of nitrosamines by alkylation of diazotates
Recent reviews. 12
Active metals from potassium-graphite. Zinc-graphite promoted synthesis of .beta.-hydroxy esters, homoallylic alcohols and .alpha.-methylene-.gamma.-butyrolactones
(N-Alkylthiocarbamoyl)phosphonic acid esters. Part 3. (N-Alkylthiocarbamoyl)thionophosphonic acid esters
Application of potential energy calculations to organic chemistry. Part 16. Further examples of enhanced lengthening of strained carbon-carbon bonds by orbital interactions
A convenient synthesis of N-vinylpyridinium perchlorate and a study of N-vinylpyridinium cations as Michael reaction acceptors
Intramolecular Wittig cyclization: a novel route to previously unknown 3-thia and 3-sulfinyl analogs of testosterone
Masthead
Mild generation of alkylidenecarbenes from (tosylazo)alkenes and silylvinyl triflates. Mode of decomposition and nature of the carbene intermediates
Configurational stability of a cyclopropyl Grignard reagent containing a metalated 2-hydroxymethyl group
Chemistry of four-membered cyclic nitrones. 5. Synthesis and oxidation of 1-hydroxyazetidines
Selective carbon-carbon bond formation via transition-metal catalysis. 34. Countercation effects on the palladium-catalyzed allylation of enolates
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