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Structure resonance theory and electrophilic reactivity of helicenes. Theoretical correlations
Synthesis and structural aspects of macrocyclic polyamines containing 2,2'-bipyridinyl units(s)
New method for the preparation of activated nickel and cobalt powders and their application in biaryl synthesis
Nitrogen effects in photoreactions. Photochemistry of iminoquinones with olefins
Studies on the reaction of mitomycin C with potassium ethyl monothiocarbonate under reductive conditions
Bromine-initiated rearrangement of 4-homoadamantanone ethylenedithioketal
Nucleophilic substitutions of unactivated vinyl halides with alkanethiolate anions in hexamethylphosphoramide
Macrocyclic receptor molecules for guanidinium cations. Preparation, x-ray structures, and kinetic stabilities of 1:1 complexes of guanidinium perchlorate with benzo-27-crown-9, dibenzo-27-crown-9, and dibenzo-30-crown-10
Organometallic methylation of nicotine and nicotine N-oxide. Reaction pathways and racemization mechanisms
Mechanism of photoepoxidation of olefins with .alpha.-diketones and oxygen
Effect of restricted mobility of the linking chain on intramolecular excimer formation
Dealkylation of a tertiary amine group by an intramolecular carbamyl chloride functionality
Oxidation of alkyl trimethylsilyl ketene acetals with lead(IV) carboxylates
An alternate synthesis of deethylvincadifformine
Chemistry of naturally occurring polyamines. 7. Selective functionalization of hydroxyputrescine
Stable carbocations. 252. The 2,3-dimethyl-3-fluoro-2-butyl cation revisited: exclusive methyl exchange ruling out fluorine shift through bridged fluoronium ion
Structure of teucroxide. Application of natural-abundance carbon-13 - carbon-13 coupling constants observed via double-quantum coherence
Chemistry of oxaziridines. 6. Hydroxylation of anisole by 2-sulfonyloxaziridines
Oxidation of alkylbenzenes by peroxydisulfate-copper(II) in acetic acid and acetonitrile
Preparation and characterization of some pentaarylethyls
Chiral acetylenes as synthetic intermediates. 4. Synthesis and chiroptical properties of optically active .alpha.,.beta.-acetylenic ketones
Catalytic activity of copper(II)-ethylenediamine complexes in autoxidation of phenols
Regiocontrolled synthesis of mono-, di-, and trisubstituted cyclohexenones by cycloaddition of vinyl sulfones to 1-methoxy-3-[(trimethylsilyl)oxy]-1,3-butadienes. Conversion of alkenes into effective dienophilic reagents
Rhodium(I)-catalyzed hydrosilylation of styrene
Homologation of acetals of .alpha.,.beta.-unsaturated carbonyl compounds with diazoesters. Synthesis of acetals of .beta.,.gamma.-unsaturated carbonyl compounds
Restricted rotation and ring-chain conformation in hindered 7-cis isomers of retinal and related compounds. A nuclear magnetic resonance study
Inverse electron demand Diels-Alder reactions of 4,6-dimethyl-2-oxo-2H-pyran-5-carboxylic acid esters and morpholino enamines: regiospecific preparation of 3- or 4-substituted-2,6-dimethylbenzoates
A pyrolytic route to the phthalide-isoquinolines
A chiral recognition model for the chromatographic resolution of N-acylated 1-aryl-1-aminoalkanes
Reactivity of benzylic carbanions. 10. [1,4]-Rearrangement of the trimethylsilyl group in 9,9-bis(trimethylsilyl)- and 9-alkyl-9-(trimethylsilyl)-10-lithio-9,10-dihydroanthracenes
Total synthesis of carbohydrates. 2. Regiochemical control of nucleophilic ring opening of acylated 2,3-epoxy alcohols
Aglycon modifications of erythromycin A and erythromycin B - regiospecific nucleophilic ring opening of cyclic thionocarbonates
Stable carbocations. 251. Carbon-13 NMR spectroscopic study of substituted anthracene dications
Competitive reactions of alkylidenetriphenylphosphoranes and methylsulfinyl carbanion with 3-methylenespiro[5.5]undeca-1,4-diene
Reactivity model for the Menschutkin reaction. Methylation of alkyl-substituted and heterosubstituted pyridines
Intramolecular catalysis in a nonhydroxylic solvent. 2. n-Butylaminolysis of catechol monoacetate and methyl (o- and p-hydroxyphenyl)acetates
"Anti-Hammond" transition-state structural variation in the context of Marcus' rate theory
Reaction of dimethyloxosulfonium methylide with epoxides. Preparation of oxetanes
Mercuric acetate cyclization of 4-(pyrrolylmethyl)- and 4-(indolylmethyl)piperidines to bridged polycyclic systems
Synthesis of highly lipophilic crown ether carboxylic acids
Intramolecular hydrogen atom transfer reactions of .omega.-formylalkyl radicals in vapor and liquid phases
Synthesis of acyl phosphonate analogs of biologically important acyl phosphates: N-(2-amino-10-methylpteroyl)-5-amino-2-oxopentanephosphonic acid
Reactions of mitomycin C with potassium ethyl xanthate in neutral aqueous solution
Synthesis of 2-methyl-3-hydroxy-4H-pyran-4-one and 4-hydroxy-5-methyl-2H-furan-3-one from carbohydrates
Organic reactions of sulfur dioxide. Reactions with nucleophilic double bonds leading to the isomerization, aromatization, selective hydrogen-deuterium exchange, and electron-transfer processes
Aerosol direct fluorination syntheses: alkyl halides, neopentyl chloride and bromide, free radicals vs. carbocations
Masthead
Electrogenerated bases. 8. Epoxidations by electrogenerated superoxide with/without auxiliary carbon acids. .alpha.,.beta.-Unsaturated ketones
Synthesis of 2,4-disubstituted pyrimidines, polypyrimidinediyls, and annulated pyrimidines
Ring-opening processes in the 8-oxabicyclo[3.2.1]octane ring system
Simple and efficient synthesis of 3-oxo-2,6,6-trimethylcyclohex-1-ene-1-carboxylic acid, a key synthon for (.+-.)-strigol
Thermolysis of 4-methyl-4-phenylmalonyl peroxide: a new oxygen dependent chemiluminescent reaction
Stereochemistry of intramolecular amidoalkylation reactions in the synthesis of polycyclic isoquinoline derivatives
Metal-promoted cyclization. 3. Highly selective synthesis of .alpha.-alkylidenetetrahydrofurans and .gamma.-alkylidenebutyrolactones via intramolecular opening of epoxysilanes
Reaction of lithioisobutyrophenone with (+)-2S-iodooctane in weakly polar aprotic solvents
Substitution at tricoordinate sulfur(IV). Rearrangement of sulfinanilides to anilino sulfoxides
Dienophilic properties of phenyl vinyl sulfone and trans-1-(phenylsulfonyl)-2-(trimethylsilyl)ethylene. Their utilization as synthons for ethylene, 1-alkenes, acetylene, and monosubstituted alkynes in the construction of functionalized six-membered rings via [4 + 2] .pi. cycloaddition methodology
Synthesis of two macrolide pheromones of the rusty grain beetle, Cryptolestes ferrugineus (Stephens)
Chemistry of naturally occurring polyamines. 8. Total synthesis of (+)-hypusine
Hydroboration. 65. Relative reactivities of representative alkenes and alkynes toward hydroboration by catecholborane
Total synthesis of carbohydrates. 3. Efficient enantioselective syntheses of 2,6-dideoxyhexoses
Synthesis of a conjugated nitrile from a benzylic ketone via a cyanotrimethylsilane adduct: 3,4-dihydro-6-methoxynaphthalene-1-carbonitrile
Synthesis and biological activity of L-5-deazafolic acid and L-deazaaminopterin: synthetic strategies to 5-deazapteridines
Oxidation of arylalkanols by peroxydisulfate-copper(II)
Tetracyclo[5.4.0.03,10.04,8]undecane (2,9-ethanonoradamantane) and 12-oxapentacyclo[6.4.0.02,6.03,11.04,9]dodecane system
Solvolysis of [4.2.2]propellan-7-yl derivatives
Synthesis and chemistry of an unusual bridgehead alkene
Alkoxide-accelerated Smiles rearrangements. Synthesis of N-(2-hydroxyethyl)anilines from N-(2-hydroxyethyl)(aryloxy)acetamides
6,2-Methyl migration in the norbornane system
Quassinoid synthesis via o-quinone Diels-Alder reactions
Electron-transfer reactions between perfluoroacyl peroxides and methoxybenzenes
Studies on the nactins: total synthesis of (.+-.)-tert-butyl 8-O-(tert-butyldimethylsilyl)nonactate
Chemistry of heterocyclic compounds. Part 83. .alpha.-Methyl functionalization of electron-poor heterocycles: 2,9-bis(chloromethyl)-1,10-phenanthroline. Synthesis of a [3.3]cyclophane containing the 1,10-phenanthrolino moiety
Ethylene biosynthesis. 1. A model for two reactive intermediates
Ring substituent effects on acetophenone dimethyl acetal formation. 1. Dual-parameter treatment of equilibrium data in methanol, water and dodecane
Synthesis of 1,1-difluoro-2-azaperhalo-1-butenes and their conversion to oxaziridines
Approaches to azepines: a new azepine by the photolysis of dimethyl p-azidosalicylate
Secondary orbital interactions determining regioselectivity in the Diels-Alder reaction. 5. Thio-substituted 1,3-butadienes
An efficient synthesis of azidoindoles and azidotryptophans
A convenient synthesis of 4-ethynylphthalic anhydride via 2-methyl-3-butyn-2-ol
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