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Pyrolysis of bicyclo[n.2.2] bridgehead acetates with a bridgehead double bond
Conversion of one hydroxy group in a diol to a phenyl ether with triphenylbismuth diacetate, a new glycol reaction showing strong axial preference in six-membered rings
Synthesis of novel-N-nitrosothioureas and examination of their mechanisms of formation by high-field nitrogen-15 and carbon-13 nuclear magnetic resonance spectra of specifically labeled compounds
New synthesis of 5,7-dihydroxy-4-methylphthalide, a key intermediate in the synthesis of mycophenolic acid
Synthesis of .beta.-lactams by the photochemical extrusion of sulfur dioxide from 1,1-dioxo-4-thiazolidinones
Sulfonamidyls. 5. Electron spin resonance spectroscopic evidence for four- and five-membered-ring sulfonamidyls and sulfonyl nitroxides
Metal-catalyzed organic photoreactions. Bond-cleavage selectivity and synthetic application of the iron(III) chloride catalyzed photooxidation of cyclic olefins
Ethylaluminum dichloride catalyzed ene reactions of aldehydes with nonnucleophilic alkenes
Electrophilic substitution with allylic rearrangement (SE'). Anti stereoselectivity in trifluoroacetolysis of some cyclohex-2-enylsilanes, -germanes and -stannanes
Electron-transfer reduction of bis(gem-dihalocyclopropyl) compounds. Evidence against the 1,4-elimination-type remote ionization of the cyclopropylidene radical anion. Unusual product distribution as a result of reactions in the region of reagent mixing
Formal total synthesis of streptonigrin
Photochemical synthesis of some propellanes through [2+2] cycloaddition of indeno[2,1-a]indene with several olefins
Synthetic approaches to 11-deoxy-7-oxaprostaglandin analogs
Regioselectivity in nickel(II)-mediated oxidations of diols
Study of the conformation of novel N-nitrosothioureas by high-field nitrogen-15 and carbon-13 nuclear magnetic resonance spectroscopy employing specifically labeled compounds
Oxidation of enol silyl ethers: preparation of aeginetolide, dihydroactinidiolide, and actinidiolide
Generation of aldehydic enol ethers and enamines by olefination of ketones
Photocyclization of stilbenes. VII. Unusual fluorine atom rearrangement in the photocyclization of 1-fluoro[5]helicenes
Nucleophilic aromatic substitution reactions under phase-transfer conditions. Synthesis of alkyl aryl sulfides from isomeric dichlorobenzenes and thiolates
Generation and ring-opening of 2,3-dilithio-1-(phenylsulfonyl)indole
Silicon-substituted dienes in the intramolecular Diels-Alder reaction: nagilactone model studies
[1 + 3] Cycloadditions of isocyanides to azomethine ylides; synthesis and properties of 1-phthalimidoazetidines
Electrophilic mercuration reactions of derivatives of deuteroporphyrin IX: new syntheses of coproporphyrin III, harderoporphyrin, isoharderoporphyrin, and S-411 porphyrin (dehydrocoproporphyrin)
Stereochemistry and regiochemistry of electron impact. Thermally and photolytically induced eliminations from 1-decalyl acetates
Quenching of singlet oxygen by 1,3,5-triaryl-2-pyrazolines
One-pot and regioselective synthesis of alkenes and deuterioalkenes from .alpha.-chlorocarboxylic acid chlorides via a tandem addition of two different nucleophiles (Grignard reagents, hydride or deuteride) and further lithiation
Preparation and properties of annelated tropylium salts
Nonhomogeneous phase effect on the generation of carbene radical anions in the Birch-type reduction of bis(gem-dihalocyclopropyl)compounds
Chemistry of four-membered cyclic nitrones. 4. Reaction with electrophilic reagents and conversion into .beta.-lactam derivatives
Molecular rearrangements. Synthesis, stability, and rearrangements of 2-imino-2H-isoxazolo[2,3-a]pyrimidines and 2-aminoisoxazolo[2,3-a]pyrimidinium salts
Cleavage of phosphate esters by hydroxyl-functionalized micellar and vesicular reagents
Masthead
Synthesis of protected 2-amino-8-oxo-9,10-epoxydecanoic acid from 2-aminosuberic acid derivatives
Quassinoids. 1. Attempted intramolecular Diels-Alder approach for assembling the ABCD rings
N-acyl-.beta.-enamino ketones: versatile heterocyclic synthons
Bridged nicotines. Synthesis of cis-2,3,3a,4,5,9b-hexahydro-1-methyl-1H-pyrrolo[2,3-f]quinoline
Photolysis of .alpha.-diazo ketones in the gas phase monitored by Fourier-transform infrared spectrometry
Stereoselectivity in organoborane rearrangement: relationship to the mechanism of hydroboration
Dehydration of 1-substituted secondary and tertiary bicyclo[3.3.1]nonan-9-ols. A substituent-driven rearrangement to 4-substituted and/or angularly substituted hexahydroindenes
Relatively fast solvolytic reactions of 1-adamantyl mesylate. Further development of the YOTs scale of solvent ionizing power and the NOTs scale of solvent nucleophilicity
SNAr nucleophilic substitutions of Cr(CO)3-complexed aryl halides with thiolates under phase-transfer conditions
Friedel-Crafts reactions of some conjugated epoxides
Electrochemical study of the oxidation of .alpha.-methyldopamine, .alpha.-methylnoradrenaline, and dopamine
Condensation-cyclization of acetoacetanilides with 1,3,5-trinitrobenzene. Formation and structure of some stable delocalized anions containing the bicyclo[3.3.1]nonane skeleton
Equilibration of 5-methyl-3-hexen-2-one and 5-methyl-4-hexen-2-one and of XCH2CH:CYZ/XCH:CHCHYZ pairs in general
On the relation between elution order and absolute stereochemistry of alkylarylcarbinols from a Pirkle column
Synthesis of novel energetic compounds. V. The use of acetyl azide as an "azidation agent"
Electrophilic substitution with allylic rearrangement (SE'). Syn-stereoselectivity in sulfur dioxide insertion into some cyclohex-2-enylstannanes
Relative donor-atom effects on rates of isomerization of 3-butenenitrile catalyzed by anions of the same basicity
Absolute stereochemistry of (-)-albene
Synthesis of 1,2,3,4,6-penta-O-acetyl-5-deoxy-5-C-[(RS)-ethylphosphinyl]-.alpha.- and .beta.-D-glucopyranoses and their structural analysis by 400-MHz proton nuclear magnetic resonance
Chemistry of higher order, mixed organocuprates. 5. On the choice of the copper(I) salt for the formation of R2CuLi
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